Orbital-resolved nonadiabatic tunneling ionization

Qingbin Zhang, Gihan Basnayake, Alexander Winney, Yun Fei Lin, Duke Debrah, Suk Kyoung Lee, and Wen Li
Phys. Rev. A 96, 023422 – Published 25 August 2017

Abstract

In this theoretical work, we show that both the orbital helicity (p+ vs p) and the adiabaticity of tunneling have a significant effect on the initial conditions of tunneling ionization. We developed a hybrid quantum (numerical solution of the time-dependent Schrödinger equation) and classical (back propagation of trajectories) approach to extract orbital-specific initial conditions of electrons at the tunneling exit. Clear physical insight connecting these initial conditions with the final momentum and deflection angles of electrons are presented. Moreover, the adiabaticity of tunneling ionization is characterized by comparing the initial conditions with those with a static field. Significant nonadiabatic tunneling is found to persist beyond a Keldysh parameter of less than 0.5.

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  • Received 7 March 2017

DOI:https://doi.org/10.1103/PhysRevA.96.023422

©2017 American Physical Society

Physics Subject Headings (PhySH)

Atomic, Molecular & Optical

Authors & Affiliations

Qingbin Zhang1,2, Gihan Basnayake1, Alexander Winney1, Yun Fei Lin1, Duke Debrah1, Suk Kyoung Lee1, and Wen Li1,*

  • 1Department of Chemistry, Wayne State University, Detroit, Michigan 48202, USA
  • 2School of Physics, Huazhong University of Science and Technology, Wuhan 430074, China

  • *wli@chem.wayne.edu

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Issue

Vol. 96, Iss. 2 — August 2017

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