Abstract
Amorphous Se85−x Te15Sb x (x = 2.5, 5 and 7.5 at.%) thin films were deposited on glass substrates by thermal evaporation. The absorption coefficient was determined from the transmittance, and reflectance spectra in the wavelength range 400–2500 nm. Various optical constants have been calculated for the studied compositions. The mechanism of the optical absorption follows the rule of non-direct transition. It was found that the optical energy gap, E g, decreases from 1.42 to 1.36 eV with increasing Sb content from 2.5 to 7.5 at.%. These results can be interpreted on the basis of the chemical bond approach proposed by Bicermo and Ovshinsky. On the other hand, the optical constants such as refractive index, n, and extinction coefficient, K ex, of the films were studied. The dispersion of the refractive index was discussed in terms of single-oscillator Wemple–DiDomenico model. The influence of Sb content on the structure for the annealed films was investigated using X-ray diffraction (XRD) and scanning electron microscopy. The average particle size of the crystalline size for Te0.04Se0.96 phase deduced from XRD pattern. This average decreases with increasing Sb content.
Similar content being viewed by others
References
S.R. Ovshinsky, H. Fritzxche, Metall. Trans. 2, 641 (1971)
M.A. Abdel-Rahim, A.H. Moharram, M. Dongol, M.M. Hafiz, J. Phys. Chem. Solids 51, 355 (1990)
G. Kaur, T. Komatsu, R. Thangaraj, J. Mater. Sci. 35, 903 (2000)
S.A. Khan, M. Zulfequar, M. Husain, Solid State Commun. 123, 463 (2002)
N. Suri, K.S. Bindra, P. Kumar, R. Thangaraj, J. Non-Cryst. Solids 353, 264 (2007)
M.A. Abdel-Rahim, A. Gaber, A.A. Abu-Sehly, N.M. Abdelazim, Ther-mochim. Acta 566, 274 (2013)
R. Chiba, N. Funakoshi, J. Non-Cryst. Solids 105, 149 (1988)
N.S. Saxena, J. Non-Cryst. Solids 345, 161 (2004)
N.B. Maharjan, K. Singh, N.S. Saxena, Phys. Status Solidi 195, 305 (2003)
M.A. Abdel-Rahim, A. Gaber, A.A. Abu-Sehly, N.M. Abdelazim, J. Non-Cryst. Solids 376, 158 (2013)
K.A. Aly, H.H. Amer, A. Dahshan, Mater. Chem. Phys. 113, 69 (2009)
S.K. Tripathi, V. Sharma, A. Thakur, J. Sharma, G.S.S. Saini, N. Goyal, J. Non-Cryst. Solids 351, 2468 (2005)
A.S. Soltan, A.A. Abu Sehly, M.A. Abdel-Rahim, J. Phys. Chem. Solids 63, 801 (2002)
A.J.P. Wilson, Mathematical theory of X-ray powder diffractometry (Cordon and Breach, New York, 1963)
M. Fox, Optical properties of solids (Oxford University Press, Oxford, 2001), p. 3
F. Urbach, Phys. Rev. 92, 1324 (1953)
S. Venkatachalam, D. Mangalaraj, S.K. Narayandass, K. Kim, J. Yi, Physica B 358, 27 (2005)
M.A. Abdel-Rahim, M.M. Hafiz, A. Elwhab, B. Alwany, Optics Laser Technol. 44, 1116 (2012)
J. Tauc (ed.), Amorphous and liquid semiconductor (Plenum Press, New York, 1974), p. 159
M. Kastner, D. Adler, H. Fritzshe, Phys. Rev. Lett. 37, 1504 (1976)
L. Pauling, The nature of the chemical bond, 3rd edn. (Cornell Univ. Press, Ithaca, NY, 1960)
Ambika, P.B. Barman, Physica B 405, 822 (2010)
J. Bicerano, S.R. Ovshinsky, J. Non-Cryst. Solids 74, 75 (1985)
P. Kumar, R. Thangaraj, Solid State Commun. 140, 525 (2006)
M.A. Abdel-Rahim, M.M. Hafiz, M.M. El-Nahass, A.M. Shamekh, Physica B 387, 383 (2007)
M. Fadel, S.S. Fouad, E.G. El-Metwally, Chalco. Lett. 5, 79 (2008)
O.A. Lafi, M.M.A. Imran, M.K. Abdullah, Physica B 395, 69 (2007)
P. Sharma, M. Vashistha, I.P. Jain, J. Optoelectron. Adv. Mater. 7, 2963 (2005)
S. Ilican, Y. Caglar, M. Caglar, M. Kundakci, A. Ates, Int. J. Hydrog. Energ. 34, 5201 (2009)
S.H. Wemple, Phys. Rev. B 8, 3767 (1973)
S.H. Wemple, M. DiDomenico, Phys. Rev. B 3, 1338 (1971)
M.M. Malik, M. Zulfequar, A. Kumar, M. Husain, J. Phys. Condens. Matter 4, 8331 (1992)
H. Ticha, L. Tichy, J. Optoelectron. Adv. Mater. 4, 381 (2002)
M.B. El-Den, M.M. El-Nahass, Optics Laser Technol. 35, 335 (2003)
Z.H. Khan, M. Zulfequar, T.P. Sharma, M. Husain, Optical Mater. 6, 139 (1996)
M.I. Abd-Elrahman, R.M. Khafagy, S.A. Zaki, M.M. Hafiz, J. Alloys compd. 571, 118 (2013)
F. Yakuphanoglu, C. Viswanthan, J. Non-Cryst. Solids 353, 2934 (2007)
P. Sharma, I. Sharma, S.C. Katyal, J. Appl. Phys. 105, 053509 (2009)
R.M. Mehra, G. Kaur, A. Pundir, P.C. Mathur, Jpn. J. Appl. Phys. 32, 128 (1993)
Author information
Authors and Affiliations
Corresponding author
Rights and permissions
About this article
Cite this article
Abdel-Rahim, M.A., Hafiz, M.M. & Mahmoud, A.Z. Effect of Sb additive on structural and optical properties of Se–Te–Sb thin films. Appl. Phys. A 118, 981–988 (2015). https://doi.org/10.1007/s00339-014-8853-x
Received:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s00339-014-8853-x