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Johnston, Scott G; Karimian, Niloofar; Burton, Edward (2020): Seasonal mobility of Arsenic and Antimony in the Macleay River 2016-2019 [dataset]. PANGAEA, https://doi.org/10.1594/PANGAEA.920582

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Abstract:
Water samples from the Macleay River were collected from Bellbrook bridge (30°49'10.58"S; 152°30'20.33"E) over a 35 month period (August 2016 to July 2019) at approximately 0.5 m below surface at mid-channel, directly into a clean (trace-grade HNO3- acid-rinsed), 1 L low density polyethylene container, pre-rinsed five times with sample water. A stratified sampling approach was employed, with samples collected every 5-7 days during ambient and low flow periods and daily (or multiple times daily) during high flow events. During high-flow periods when the bridge was submerged, samples were collected from the river bank using a 4 m extendable sample pole placed as far as possible into a turbulent part of the main flow. Water samples were filtered (0.45 µm; enclosed syringe filter) and filtered aliquots preserved using ultra-pure HCl, prior to analysis for As and Sb by ICP-MS (Perkin-Elmer ELAN-DRCe). Cl- and SO42- were analysed via via ion chromatography (Metrosep A Supp4-250 column, an RP2 guard column and eluent containing 2 mM NaHCO3, 2.4 mM Na2CO3 and 5% acetone, in conjunction with a Metrohm MSM module for background suppression). Mean daily river discharge was recorded at Georges Junction gauging station (NSW Water, station #206024, 30°45'6.71"S; 152°12'17.96"E). Mean daily water temperature in the Macleay River was recorded at Kempsey by automatic logger (NSW Water, station #206402, 31° 4'50.98"S; 152°50'33.05"E).
Keyword(s):
antimony; arsenic; Macleay River; Redox potential; Temperature
Related to:
Johnston, Scott G; Karimian, Niloofar; Burton, Edward (2020): Seasonal Temperature Oscillations Drive Contrasting Arsenic and Antimony Mobilization in a Mining‐Impacted River System. Water Resources Research, 56(10), e2020WR028196, https://doi.org/10.1029/2020WR028196
Coverage:
Median Latitude: -30.883115 * Median Longitude: 152.245750 * South-bound Latitude: -30.892140 * West-bound Longitude: 151.467830 * North-bound Latitude: -30.874090 * East-bound Longitude: 153.023670
Date/Time Start: 2016-08-02T20:44:00 * Date/Time End: 2019-07-26T16:05:00
Event(s):
Macleay_River * Latitude Start: -30.892140 * Longitude Start: 151.467830 * Latitude End: -30.874090 * Longitude End: 153.023670 * Date/Time Start: 2016-10-24T17:50:00 * Date/Time End: 2019-07-26T16:05:00 * Location: Macleay River * Method/Device: Multiple investigations (MULT)
Parameter(s):
#NameShort NameUnitPrincipal InvestigatorMethod/DeviceComment
1DATE/TIMEDate/TimeJohnston, Scott GGeocode
2Temperature, waterTemp°CJohnston, Scott GTemperature logger (TLOG)at Kempsey (-31.08083,152.84251)
3ArsenicAsµg/lJohnston, Scott GICP-MS, Perkin-Elmer, ELAN-DRCeat Bellbrook (-30.81961, 152.50565)
4AntimonySbµg/lJohnston, Scott GICP-MS, Perkin-Elmer, ELAN-DRCeat Bellbrook (-30.81961, 152.50565)
5Chloride/sulfate ratioCl/[SO4]2-Johnston, Scott GIon chromatographyat Bellbrook (-30.81961, 152.50565)
6River dischargeQm3/sJohnston, Scott GRiver gauging station (RGS)at Georges Junction (-30.75186,152.20499)
Size:
1198 data points

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