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Photophysical properties of a crown ether-bearing [60]fulleropyrrolidine

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Abstract.

The photophysical properties of the first crown ether-bearing [60]fulleropyrrolidine (CFP) have been studied. The absorption and fluorescence spectra are hypsochromically shifted by metal ions complexation via intramolecular electron transfer which is confirmed by AMI computation. The third-order optical nonlinearity of CFP is measured by time-resolved degenerate four-wave-mixing experiment. The third-order optical susceptibility χ(3) of CFP is 8.97×10−14 esu. The nonlinear optical temporal response is second-order exponential, the fast process is determined as 120 ps.

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Authors and Affiliations

  1. Institute of Chemistry, Chinese Academy of Sciences, Beijing 100080, P.R. China, , , , , , CN

    Z. Guo, Y. Li, J. Yan, F. Bai, F. Li & D. Zhu

  2. Institute of Physics, Chinese Academy of Sciences, Beijing 100080, P.R. China (Fax: +86-10/6255-9373, E-mail: ylli@home.icm.ac.cn), , , , , , CN

    J. Si & P. Ye

Authors
  1. Z. Guo
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  2. Y. Li
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  3. J. Yan
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  4. F. Bai
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  5. F. Li
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  6. D. Zhu
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  7. J. Si
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  8. P. Ye
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Received: 24 March 1999 / Revised version: 11 May 1999 / Published online: 25 August 1999

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Guo, Z., Li, Y., Yan, J. et al. Photophysical properties of a crown ether-bearing [60]fulleropyrrolidine . Appl Phys B 70, 257–260 (2000). https://doi.org/10.1007/s003400050042

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  • DOI: https://doi.org/10.1007/s003400050042

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