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Intramolecular charge transfer complexes

7. Radical copolymers of 2,4-dinitrophenyl methacrylate with n-(2-hydroxyethyl)-3,6-dichlorocarbazolyl acrylate and methacrylate

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Summary

Radical copolymerization of 2,4-dinitrophenyl methacrylate (DNPM, M2) with N-(2-hydroxyethyl)-3,6-dichlorocarbazolyl methacrylate (HECl2CM, m1) and N-(2-hydroxyethyl)-3,6-dichloro-carbazolyl acrylate (HEC12CA, M1) takes place by the simple terminal mechanism having the parameters: r1=0.13 r2=1.65 (M1=HECl2CM) r1=0.13 r2=1.20 (M1=HECl2CA) Intramolecular complexation differences for the two obtained systems are explained by configurational differences.

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Authors and Affiliations

  1. “P. Poni” Institute of Macromolecular Chemistry, 6600, Jassy, Rumania

    V. Percec, A. Natansohn, V. Barboiu, B. C. Simionescu & D. Galea

Authors
  1. V. Percec
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  2. A. Natansohn
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  3. V. Barboiu
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  4. B. C. Simionescu
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  5. D. Galea
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Dedicated to our Prof. C.I. Simionescu in occasion of his 60th anniversary

6th part in this series: reference (6)

Abbrevuiations The monomer mixture is indicated by the initials of the two monomers (for example HECA-PM) and their copolymer by the initials separated by -co- (for example HECA-co-PM).

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Percec, V., Natansohn, A., Barboiu, V. et al. Intramolecular charge transfer complexes. Polymer Bulletin 2, 505–511 (1980). https://doi.org/10.1007/BF00255252

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  • DOI: https://doi.org/10.1007/BF00255252

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