Abstract
This work has been devoted to a mass spectrometric investigation of the interaction of atmospheric oxygen or an air-methane mixture with molten V2O5-NaPO3, selected as a model catalyst; the work has been further aimed at studying the reaction mechanisms. The data on the change in isotope composition18O/16O have been analyzed, and the rate constants and order of reaction with respect to oxygen have been determined.A mechanism has been proposed for the interaction of both atmospheric oxygen and the air-methane mixture with the melt.
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Institute of General and Inorganic Chemistry, Academy of Sciences of the Ukrainian SSR, Kiev. Translated from Teoreticheskaya i Éksperimental'naya Khimiya, No. 1, pp. 99–104, January–February, 1991. Original article submitted May 3, 1990.
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Volkov, S.V., Bandur, V.A. & Buryak, N.I. Mass spectrometric investigation of reactions of oxygen exchange and partial oxidation of methane in molten catalysts. Theor Exp Chem 27, 94–99 (1991). https://doi.org/10.1007/BF01372932
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DOI: https://doi.org/10.1007/BF01372932