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Oxidation of dicyclopentadiene catalyzed by palladium(II) acetate and p-benzoquinone in the presence of inorganic acid

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Abstract

The oxidation of dicyclopentadiene catalyzed by palladium(II) acetate and benzoquinone in the presence of perchloric acid was studied. Tricyclodecenone in high selectivity (85–98%) at a conversion of dicyclopentadiene up to 76% was obtained. The kinetic model assumed the significant inhibition complexation between dicyclopentadiene and tricyclodecenone with the catalytic species.

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Authors
  1. M. Skumov
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  2. E. Balbolov
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Skumov, M., Balbolov, E. Oxidation of dicyclopentadiene catalyzed by palladium(II) acetate and p-benzoquinone in the presence of inorganic acid. Catalysis Letters 69, 103–107 (2000). https://doi.org/10.1023/A:1019053402854

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  • DOI: https://doi.org/10.1023/A:1019053402854

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