Abstract
The complexation of protonated hexacyclen and pentacyclen with pyrophosphate, selenite, selenate, molybdate and tungstate anions was studied by differential pulse polarography at 25 °C. The stoichiometry and stability of the resulting anion complexes were evaluated from the pH and concentration-dependence of the peak potentials, respectively. The results established 1 : 1 anion receptor complexation in all cases. In the case of all anions studied, hexacyclen was found to form more stable anion complexes than pentacyclen. The fact that the anion-receptor complexation depends on the structural features of both the anions and the macrocycles used is indicative of a steric controlled interaction.
This is a preview of subscription content, log in via an institution to check access.
Similar content being viewed by others
References
J. M. Lehn: in Biomimetic Chemistry (Eds. N. Ise and Z. I. Yoshida), Elsevier, Amsterdam (1983).
E. Kimura: Topics Curr. Chem. 128, 113 (1985).
J. J. Christensen and R. M. Izatt (Eds.): Synthesis of Macrocycles, the Design of Selective Complexing Agents, Wiley, New York (1987).
R. M. Izatt, K. Pawlak, R. L. Bruening and J. S. Bradshaw: Chem. Rev. 91, 1721 (1991).
R. M. Izatt, K. Pawlak, J. S. Bradshaw, and R. L. Bruening: Chem. Rev. 95, 2529 (1995).
F. P. Schmidtchen and M. Berger: Chem. Rev. 97, 1609 (1997).
E. Kimura, A. Sakonaka, T. Yatsunami and M. Kodoma: J Am. Chem. Soc. 103, 3041 (1981).
E. Kimura, M. Kodama, and T. Yatsunami: J. Am. Chem. Soc. 104, 3182 (1982).
J. Gullinane, R. I. Gelb, T. N. Margulis, and L. J. Zompa: J. Am. Chem. Soc. 104, 3048 (1982).
R. I. Gelb, B. T. Lee, and L. J. Zompa: J. Am. Chem. Soc. 107, 909 (1985).
R. I. Gelb, L. M. Schwartz, and L. J. Zompa: Inorg. Chem. 25, 1527 (1986).
M. W. Hosseini and J. M. Lehn: Helv. Chim. Acta 70, 1312 (1987).
H. Jahansouz, Z. Jiang, R.H. Himes, M.P. Mertes and K.B. Mertes: J. Am. Chem. Soc. 111, 1409 (1989).
E. Kimura, Y. Kuramoto, T. Koike, H. Fujioka and M. Kodama: J. Org. Chem. 55, 42 (1990).
J. Arago, A. Bencini, A. Bianchi, A. Domenech, and E. Garcia-Espana: J. Chem. Soc., Dalton Trans. 319 (1992).
G. Wu, R. M. Izatt, M. L. Bruening, W. Jiang, H. Azab, K. E. Krakowiak, and J. S. Bradshaw: J. Incl. Phenom. 15, 121 (1992).
A. Andres, C. Bazzicalupi, A. Bencini, A. Bianchi, V. Fusi, E. Garcia-Espana, C. Giorgi, N. Nardi, P. Paoletti, J. A. Ramirez, and B. Valtancoli: J. Chem. Soc., Perkin Trans. 2 2367 (1994).
A. Bencini, A. Bianchi, C. Giorgi, P. Paoletti, B. Valtancoli, V. Fusi, E. Garcia-Espana, J. M. Llinares, and J. A. Ramirez: Inorg Chem. 35, 1114 (1996).
B. Dietrich, B. Dilworth, J. M. Lehn, and J.P. Pascards: Helv. Chim. Acta 79, 569 (1996).
E. Lada, S. Filipek, and M. K. Kalinowski: Aust. J. Chem. 41, 437 (1988).
H. Parham and M. Shamsipur: J. Electroanal. Chem. 314, 71 (1991).
A. Semnani and M. Shamsipur: J. Electroanal. Chem. 315, 95 (1991).
A. Rouhollahi, M. Shamsipur, and M. K. Amini: Talanta 41, 1465 (1994).
M. R. Ganjali, H. Eshghi, H. Sharghi and M. Shamsipur: J. Electroanal. Chem. 405, 177 (1996).
M. Kodama and E. Kimura: J Chem. Soc., Dalton Trans. 2335 (1976).
M. Kodama and E. Kimura: J. Chem. Soc., Dalton Trans. 1081 (1978).
D. R. Crow: Polarography of Metal Complexes, Academic Press, New York (1969).
A. Bianchi, M. Micheloni, P. Orioli, P. Paoletti, and S. Mangani: Inorg. Chim. Acta 146, 153 (1988).
M. R. da Silva, B. Szpoganicz, M. Lamotte, O. F. X. Donard, and F. Fages: Inorg. Chim. Acta 236, 189 (1995).
F. A. Cotton and G. Wikinson: Advanced Inorganic Chemistry, 3rd edn., Interscience, New York (1973).
Author information
Authors and Affiliations
Rights and permissions
About this article
Cite this article
Salimi, A., Shamsipur, M. Polarographic Studies on Anion Coordination Chemistry. Host–Guest Interactions of Hexacyclen and Pentacyclen with Pyrophosphate, Selenite, Selenate, Molybdate and Tungstate Anions. Journal of Inclusion Phenomena 34, 455–464 (1999). https://doi.org/10.1023/A:1008050909119
Issue Date:
DOI: https://doi.org/10.1023/A:1008050909119