Skip to main content
SpringerLink
Log in

Host-guest sensory system of sodium anthranilate-modifiedβ-cyclodextrin: Molecular recognition properties

  • Review Article
  • Published:
Journal of inclusion phenomena and molecular recognition in chemistry Aims and scope Submit manuscript

Abstract

Sodium anthranilate-modifiedβ-cyclodextrin (1) has been prepared as a sensor for detecting organic compounds including terpenoids and steroids.1 shows a pure monomer fluorescence whose intensity is increased or decreased upon addition of the guest species examined. In this system, the sodium anthranilate moiety acts either as a spacer, which enables the cyclodextrin to form a 1∶1 guest complex by narrowing theβ-cyclodextrin cavity or acts as a hydrophobic cap.1 shows a higher sensitivity for terpenoids than for steroids, but has a higher selective molecular recognition ablity for steroids than for terpenoids.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. M.L. Bender and M. Komiyama:Cyclodextrin Chemistry, Springer Verlag (1978).

  2. A. Ueno, F. Moriwaki, T. Osa, F. Hamada and K. Mural:J. Am. Chem. Soc. 110, 4323 (1988) and references therein.

    Google Scholar 

  3. A. Ueno, S. Minato, I. Suzuki, M. Fukushima, M. Okhubo, T. Osa, F. Hamada and K. Murai:Chem. Lett., 605 (1990); Y. Wang, T. Ikeda, A. Ueno and F. Toda:Chem. Lett., 863 (1992); F. Hamada, Y. Kondo, R. Ito, I. Suzuki, T. Osa and A. Ueno:J. Incl. Phenom. 15, 273 (1993); K. Hamasaki, H. Ikeda, A. Nakamura, A. Ueno, F. Toda, I. Suzuki and T. Osa:J. Am. Chem. Soc. 115, 5035 (1993).

  4. A. Ueno, I. Suzuki and T. Osa:Anal. Chem. 62, 2461 (1990).

    Google Scholar 

  5. A. Ueno, Y. Tomita and T. Osa:J. Chem. Soc., Chem. Commun., 976 (1983).

  6. A. Ueno, F. Moriwaki, T. Matsue, T. Osa, F. Hamada and K. Murai:Makromol. Chem., Rapid Commun. 6, 231 (1985); A. Ueno, F. Moriwaki, T. Osa, F. Hamada and K. Murai:Bull. Chem. Soc. Jpn. 59, 465 (1986).

    Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Department of Material Engineering and Applied Chemistry, Mining College, Akita University, Tegata, 010, Akita, Japan

    Fumio Hamada, Yoshihiko Kondo & Kyoko Ishikawa

  2. Medical Course, School of Medicine, Akita University, Hondo, 010, Akita, Japan

    Hideaki Ito

  3. Pharmaceutical Institute, Tohoku University, Aobayama, 980, Sendai, Japan

    Iwao Suzuki & Tetsuo Osa

  4. Department of Bioengineering, Faculty of Bioscience and Biotechnology, Tokyo Institute of Technology, 4259 Nagatsuta, Midori-ku, 227, Yokohama, Japan

    Akihiko Ueno

Authors
  1. Fumio Hamada
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. Yoshihiko Kondo
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. Kyoko Ishikawa
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. Hideaki Ito
    View author publications

    You can also search for this author in PubMed Google Scholar

  5. Iwao Suzuki
    View author publications

    You can also search for this author in PubMed Google Scholar

  6. Tetsuo Osa
    View author publications

    You can also search for this author in PubMed Google Scholar

  7. Akihiko Ueno
    View author publications

    You can also search for this author in PubMed Google Scholar

Rights and permissions

Reprints and permissions

About this article

Cite this article

Hamada, F., Kondo, Y., Ishikawa, K. et al. Host-guest sensory system of sodium anthranilate-modifiedβ-cyclodextrin: Molecular recognition properties. J Incl Phenom Macrocycl Chem 17, 267–275 (1994). https://doi.org/10.1007/BF00708786

Download citation

  • Received:

  • Accepted:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF00708786

Key words

Search

Navigation