Skip to main content
SpringerLink
Log in

Mössbauer study of a novel binuclear Fe(II/III) delocalized-valence compound

  • Part I Chemical Structure and Bonding
  • Published:
Hyperfine Interactions Aims and scope Submit manuscript

Abstract

In this paper, we briefly summarize the main conclusions of the Mössbauer analysis of [L2Fe2(μ-OH)3] (ClO4)2·2CH3OH·2H2O with L=N,N',N"-trimethyl-1,4,7-triazacyclononane, a novel dimeric iron compound, which possesses a central exchange-coupled delocalized-valence Fe(II/III) unit. The complete delocalization of the excess electron in the dimeric iron center is concluded from the indistinguishability of the two iron sites in Mössbauer spectroscopy. The magnetic Mössbauer spectra imply a system spinS t=9/2 for the dimer in its ground state. The values for hyperfine and spin-Hamiltonian parameters, obtained from simulations of the Mössbauer spectra, are δ=0.74 mms−1, ΔE Q=−2.14 mms−1,A ⊥=−10.6 T,A ∥=−13.5 T andD=1.8 cm−1. The system spinS t=9/2 is interpreted to be a consequence of double-exchange coupling.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

Réferences

  1. K.Y. Wong and P.N. Schatz, Prog. Inorg. Chem. 28 (1981) 369.

    Article  Google Scholar 

  2. C. Zener, Phys. Rev. 82 (1951) 403.

    Article  ADS  Google Scholar 

  3. G.H. Jonker and J.H. van Santen, Physica 16 (1950) 337; ibid. 16 (1950) 599.

    Article  ADS  Google Scholar 

  4. P.W. Anderson and H. Hasegawa, Phys. Rev. 100 (1955) 675.

    Article  ADS  Google Scholar 

  5. S. Drüeke, P. Chaudhuri, K. Pohl, K. Wieghardt, X.-Q. Ding, E. Bill, A. Sawaryn, A.X. Trautwein, H. Winkler and S.J. Gurman, J. Chem. Soc., Chem. Comm. 59 (1989).

  6. P. Gütlich, R. Link and A.X. Trautwein, in:Mössbauer Spectroscopy in Transition Metal Chemistry (Springer, Heidelberg, 1978).

    Book  Google Scholar 

  7. N.N. Greenwood and T.C. Gibb, in:Mössbauer Spectroscopy (Chapman & Hall, London, 1971).

    Book  Google Scholar 

  8. X.-Q. Ding, E.L. Bominaar, E. Bill, H. Winkler, A.X. Trautwein, S. Drüeke, P. Chaudhuri and K. Wieghardt, J. Chem. Phys., in print.

  9. L. Noodleman and E.J. Baerends, J. Am. Chem. Soc. 106 (1984) 2316.

    Article  Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Institut für Physik, Medizinische Universität, 2400, Lübeck, FRG

    X. -Q. Ding, E. L. Bominaar, E. Bill, H. Winkler & A. X. Trautwein

  2. Lehrstuhl für Anorg. Chemie I, Ruhr-Universität, 4630, Bochum, FRG

    S. Drüeke, PH. Chaudhuri & K. Wieghardt

Authors
  1. X. -Q. Ding
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. E. L. Bominaar
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. E. Bill
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. H. Winkler
    View author publications

    You can also search for this author in PubMed Google Scholar

  5. A. X. Trautwein
    View author publications

    You can also search for this author in PubMed Google Scholar

  6. S. Drüeke
    View author publications

    You can also search for this author in PubMed Google Scholar

  7. PH. Chaudhuri
    View author publications

    You can also search for this author in PubMed Google Scholar

  8. K. Wieghardt
    View author publications

    You can also search for this author in PubMed Google Scholar

Rights and permissions

Reprints and permissions

About this article

Cite this article

Ding, X.Q., Bominaar, E.L., Bill, E. et al. Mössbauer study of a novel binuclear Fe(II/III) delocalized-valence compound. Hyperfine Interact 53, 311–315 (1990). https://doi.org/10.1007/BF02101058

Download citation

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF02101058

Keywords

Search

Navigation