Summary
-
1.
We have described the infrared absorption spectra of oxyfluorides of titanium, zirconium, hafnium, vanadium, and niobium and also zirconium dioxide (in the solid state).
-
2.
We have shown the existence of vanadyl, zirconyl, and hafnyl groups and have confirmed the existence of a niobyl group. The chains . -Ti-O-Ti- . are present in titanium oxyfluoride.
-
3.
The HfO bond strength is greater than that of ZrO, which is presumably due to the reduction of the MO bond on transition from hafnium to zirconium.
This is a preview of subscription content, log in via an institution to check access.
Similar content being viewed by others
Literature cited
C. G. Barraclough, J. Lewis, and R. S. Nyholm, J. Chem. Soc. 1959, 3552.
W. H. Zachariasen, Acta Crystallogr.7, 795 (1954).
M. E. Dyatkina, V. P. Markov, I. V. Tsapkina, and Yu. N. Mikhailov, Zh. neorgan. khimii6, 575 (1961).
S. P. McGlynn and J. R. Smith, J. Molec. Spectroscopy6, 164 (1961).
L. H. Jones and R, A. Penneman, J. Chem. Phys.21, 542 (1953).
L. Sacconi, G. Carotti, and P. Paoletti, J. Chem. Soc. 1958, 4257.
L. B. Asprey, F. H. Ellinger, and W. H. Zachariasen, J. Amer. Chem. Soc.76, 5235 (1954).
F. H. Ellinger and W. H. Zachariasen, J. Phys. Chem.58, 405 (1954).
P. Babu Rao and K. Steerama Murty, Current Sci.29, 14 (1960).
H. J. Eichoff and F. Weigel, Z. anorgan. Chem.275, 267 (1954).
W. E. Hobbs, J. Chem. Phys.28, 1220 (1958).
K. V. Narasimhan, Indian J. Phys.34, 432 (1960).
F. A. Miller and L. R. Cousins, J. Chem. Phys.26, 329 (1957).
F. A. Miller and W. K. Baer, Spectrochim. Acta17, 112 (1961).
J. Selbin, L. H. Holmes, and S. P. McGlynn, Chemistry and Industry22, 746 (1961).
Yu. A. Buslaev, V. A. Bochkareva, and N. S. Nikolaev, Izv. AN SSSR. Otd. khim. n. 1962, No. 3.
Yu. A. Buslaev, Yu. E. Gorbunova, and M. P. Gustyakova, Izv. AN SSSR. Otd. khim. n. 1962, No. 2.
G. Lundgren, Arkiv Kemi10, 397 (1957).
P. Corradini and G. Allegra, J. Amer. Chem. Soc.81, 5510 (1959).
J. L. Hoard and W. J. Martin, J. Amer. Chem, Soc.63, 11 (1941).
M. B. Williams and J. L. Hoard, J. Amer. Chem. Soc.(64, 1139 (1942).
J. D. McCullough and K. N. Trueblood, Acta Crystallogr.12, 507 (1959).
Yu. Ya. Kharitonov and I. A. Rozanov, Izv. AN SSSR. Otd. Khim. n. 1962, 402.
A. Clearfield and P. A. Vaughan, Acta Crystallogr.9, 555 (1960).
T. N. Waters, J. Inorg. and Nucl. Chem.15, 320 (1960). All abbreviations of periodicals in the above bibliography are letter-by-letter transliterations of the abbreviations as given in the original Russian journal.Some or all of this periodical literature may well be available in English translation. A complete list of the cover-to-cover English translations appears at the back of this issue.
Author information
Authors and Affiliations
Rights and permissions
About this article
Cite this article
Kharitonov, Y.Y., Buslaev, Y.A. Infrared absorption spectra of oxyfluorides of some metals of the fourth and fifth groups of the periodic table. Russ Chem Bull 11, 365–372 (1962). https://doi.org/10.1007/BF00909522
Received:
Issue Date:
DOI: https://doi.org/10.1007/BF00909522