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The reaction of titanium dioxide with hydrofluoric acid

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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Summary

  1. 1.

    We have determined the solubility of TiO2 in hydrofluoric acid solutions containing between 0 and 39.6% HF and we have proved the formation of titanium oxyfluoride of compositions TiOF2 · H2O in the form of a solid phase.

  2. 2.

    Using methods of conductometry, cryoscopy, and the measurement of electrical conductivity we have demonstrated the existence in the solution of fluorotitanic acids H[TiF4(OH)H2O], H[TiF5 · H2O], and H2[TiF6].

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Authors and Affiliations

  1. N. S. Kurnakov Institute of General and Inorganic Chemistry, Academy of Sciences, USSR

    Yu. A. Buslaev, V. A. Bochkareva & N. S. Nikolaev

Authors
  1. Yu. A. Buslaev
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  2. V. A. Bochkareva
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  3. N. S. Nikolaev
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Buslaev, Y.A., Bochkareva, V.A. & Nikolaev, N.S. The reaction of titanium dioxide with hydrofluoric acid. Russ Chem Bull 11, 361–364 (1962). https://doi.org/10.1007/BF00909521

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  • DOI: https://doi.org/10.1007/BF00909521

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