Abstract
We discuss the influence of several definitions of the dividing surface on the size dependence of surface tension and surface stress. Among others we apply the original definition of Gibbs for the “surface of tension” (SOT) and the “equimolecular dividing surface” (EMDS). We show that from physical reasons the surface tension must only include curvature terms up to the quadratic term. The considerations are illustrated for microclusters of simple geometric configurations.
Similar content being viewed by others
References
Gibbs, J.W.: Collected works. Vol. I, p. 219. New York: Longmans Green & Co. 1929
Tolman, R.C.: J. Chem. Phys.17 333 (1949)
Ono, S., Kondo, S.: In: Encyclopedia of physics. Flügge, S. (ed.). Vol. X, p. 145. Berlin, Göttingen, Heidelberg: Springer 1960
Vogelsberger, W., Müller, E.: Phys. Status Solidi B155, K17 (1989)
Shuttleworth, R.: Proc. Phys. Soc. London Sect. A63 444 (1950)
Müller, E., Vogelsberger, W., Fritsche, H.-G.: Cryst. Res. Technol.23 1153 (1988)
Parlange, J.Y.: J. Cryst. Growth6 311 (1970)
Heermann, D.W.: J. Statist. Phys.29 631 (1982)
Author information
Authors and Affiliations
Rights and permissions
About this article
Cite this article
Vogelsberger, W., Müller, E. Some problems concerning the definition of a dividing surface and its influence on the calculation of thermodynamical parameters of small clusters. Z Phys D - Atoms, Molecules and Clusters 20, 353–355 (1991). https://doi.org/10.1007/BF01544009
Received:
Accepted:
Issue Date:
DOI: https://doi.org/10.1007/BF01544009