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HPLC resolution of the enantiomers of glycidyl sulfides and glycidyl selenides on amylose tris-(phenylcarbamate) stationary phase

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Summary

The resolution of the enantiomers of a series of glycidyl sulfides and glycidyl selenides has been examined on a chiral stationary phase prepared by coating aminopropylated silica gel with amylose tris-(phenylcarbamate). Most of the enantiomers of glycidyl monosulfides and monoselenides could be resolved satisfactorily but those of the disulfides could not. The effects of solute structure and of the concentration of 2-propanol in the mobile phase on retention and resolution were investigated.

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Authors and Affiliations

  1. Lanzhou Institute of Chemical Physics, Chinese Academy of Sciences, 730000, Lanzhou, China

    Yu Zhaowen, Zhou Zhiqiang, Liu Yueqi, Jiang Shengxiang & Chen Liren

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  1. Yu Zhaowen
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  2. Zhou Zhiqiang
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  3. Liu Yueqi
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  4. Jiang Shengxiang
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  5. Chen Liren
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Zhaowen, Y., Zhiqiang, Z., Yueqi, L. et al. HPLC resolution of the enantiomers of glycidyl sulfides and glycidyl selenides on amylose tris-(phenylcarbamate) stationary phase. Chromatographia 49, 572–574 (1999). https://doi.org/10.1007/BF02467762

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  • DOI: https://doi.org/10.1007/BF02467762

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