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Preparation and characterization ofp-tert-butyl-calix[6]arene-bonded silica gel stationary phase for high-performance liquid chromatography

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Summary

For the first time calix[6]arene has been chemically combined with silica gel via a longer spacer to prepare calix[6]arene-bonded silica gel stationary phase for high-performance liquid chromatography (HPLC). The separation of positional isomers and polycyclic aromatic hydrocarbons on the calix[6]arene-bonded phase was achieved with methanol-water as mobile phase. Some nucleosides were also separated on the bonded phase. The reversed-phase chromatographic performance of the bonded phase was studied. The results showed that the calix[6]arene-bonded phase was highly hydrophobic. A possible separation mechanism has been proposed.

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Authors and Affiliations

  1. Department of Chemistry, Wuhan University, 430072, Wuhan, P.R. China

    W. Xu, J. -S. Li, Y. -Q. Feng, S. -L. Da, Y. -Y. Chen & X. -Z. Xiao

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  1. W. Xu
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  2. J. -S. Li
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  3. Y. -Q. Feng
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  4. S. -L. Da
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  5. Y. -Y. Chen
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  6. X. -Z. Xiao
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Xu, W., Li, J.S., Feng, Y.Q. et al. Preparation and characterization ofp-tert-butyl-calix[6]arene-bonded silica gel stationary phase for high-performance liquid chromatography. Chromatographia 48, 245–250 (1998). https://doi.org/10.1007/BF02467678

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  • DOI: https://doi.org/10.1007/BF02467678

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