Summary
A new automatic method is described for quantitative determination of some light C2–C4 hydrocarbons in urban air: ethene, ethyne, propane, propene, butane and iso-butane. This method is based on an enrichment step at room temperature using a solid sorbent and subsequent thermal desorption for gas chromatographic separation and FID detection. The instrument is built up of a small commercial gas chromatograph and a laboratory-made trap and desorption unit. The sampling parameters, sample volume, concentration and humidity of air have been investigated.
Similar content being viewed by others
References
Photochemical smog — Contribution of volatile organic compounds., OECD report ISBN-64-12297-4 (1982).
M. Törnqvist, A. Kautiainen, R. N. Gatz, L. Ehrenberg, J. Appl. Toxicol.8, 159 (1988)
A. M. Mohan Rao, A. J. Netravalkar, P. K. Arora, K. G. Vohra, Atmos Environ.17, 1093 (1983).
F. Bruner, P. Ciccioli, F. Di Nardo, J. Chromatog.99, 661 (1974).
R. A. Cudney, E. G. Walther, W. C. Malm, J. Air Pollut. Contr. Assoc.27, 468 (1977).
J. Rudolph, D. H. Ehhalt, A. Khedim, C. Jebsen, J. Chromatog.217, 291 (1981).
H. H. Westberg, R. A. Rasmussen, M. Holdren, Anal. Chem.46, 1852 (1974).
R. Jeltes, E. Burghardt, Atmos. Environ.6, 793 (1972).
Y. Yokouchi, T. Fujii, Y. Ambe, K. Fuwa, J. Chromatog.180, 133 (1979).
K-A, Persson, J. Almen, in “Chemical and biological characterization of urban air”, SNV PM (in English) in preparation, National Swedish Environment Protection Board, Solna, Sweden.
Author information
Authors and Affiliations
Rights and permissions
About this article
Cite this article
Persson, K.A., Berg, S. Automatic determination of selected C2–C4 hydrocarbons in urban air by solid sorbent sampling and gas chromatography. Chromatographia 27, 55–59 (1989). https://doi.org/10.1007/BF02290406
Received:
Accepted:
Issue Date:
DOI: https://doi.org/10.1007/BF02290406