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Reaktion von primären Alkylhydroperoxiden mit Amidoschwefelsäurechlorid: Alkyl(amidosulfonyl)peroxide

Reaction of primary alkyl hydroperoxides with sulphamoyl chloride: Alkyl(sulphamoyl)peroxides. Peroxo compounds, XVIII

Über Peroxoverbindungen, 18. Mitt.

  • Anorganische Und Physikalische Chemie
  • Published:
Monatshefte für Chemie / Chemical Monthly Aims and scope Submit manuscript

Abstract

The novel peroxides H2NSO2OOCH2 R (1 a:R=CH2CH3;1 b:R=CH2CH2CH3) are obtained by reaction of sulphamoyl chloride with the appropriate hydroperoxides in the presence of pyridine (temperature below −30 °C, solvent diethyl ether). The solvent-free liquids1 deflagrate at ca. 0 °C. Hydrolysis or ammonolysis of1 generates the hydroperoxide and sulphamic acid or sulphamide, respectively. Controlled thermolysis of1 affords sulphamic acid and carbonyl compounds, i.e. propanal andn-propyl propanoate from1 a, butanal, 2-methylpropanal andn-butyln-butyrate from1 b. These products suggest a nonradical cyclic decomposition path-way.

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Authors and Affiliations

  1. Institut für Anorganische und Analytische Chemie, Technische Universität, D-3300, Braunschweig, Bundesrepublik Deutschland

    Armand Blaschette & Hassan Safari

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  1. Armand Blaschette
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  2. Hassan Safari
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Blaschette, A., Safari, H. Reaktion von primären Alkylhydroperoxiden mit Amidoschwefelsäurechlorid: Alkyl(amidosulfonyl)peroxide. Monatsh Chem 115, 875–880 (1984). https://doi.org/10.1007/BF00798755

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  • DOI: https://doi.org/10.1007/BF00798755

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