Summary
The effect of chemical network on the diffusion and reaction rates of end-labeled polystyrenes in semidilute region has been measured by phosphorescence quenching technique with a 10-ns nitrogen-laser pulse, and is discussed in comparison with the results for linear polystyrene solution. The quenching rates between end-labeled polymers in semidilute region are influenced much by the formation of chemical crosslinks between the inert polymer chains.
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Mita, I., Horie, K. & Masuda, M. Diffusion and intermolecular reaction rates of end-labeled polystyrenes in polymer networks studied with triplet probe. Polymer Bulletin 4, 369–374 (1981). https://doi.org/10.1007/BF00254967
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DOI: https://doi.org/10.1007/BF00254967