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Influence of ceria coatings on growth stresses developed in wüstite scales formed on pure iron at 800°C

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Abstract

In situ XRD stress determinations have been performed during oxidation of pure iron (p(O2=2 × 10−3 Pa,T=800°C)). The compressive stress, initially present in the substrate due to surface preparation, is completely released at 400°C. Under the test conditions, the in situ compressive-stress level determined in the FeO scale during oxidation is not strongly dependent upon the presence of a ceria coating. On blank and coated specimens, the compressive stress varies from −400 ± 80 MPa to −150 ± 100 MPa during 30 hr oxidation. The decrease is quicker at the beginning of the test performed on blank specimens. Epitaxial relationships between the wüstite scale and iron (under low-pressure starting conditions) caused thein situ compressive stress in the oxide scale to be two times greater compared to the usual test conditions. This indicates that epitaxial relationships can be a source of stress in an oxide scale that ceria coatings may lower compressive stresses.

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  1. Laboratoire de Recherches sur la Réactivité des Solides, UMR 56-13 CNRS, UFR Sciences et Techniques, 9 avenue Alain Savary, BP 400, 21 011, Dijon Cedex, France

    H. Buscail, E. Sciora, J. P. Larpin & N. Gerard

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  1. H. Buscail
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  2. E. Sciora
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  3. J. P. Larpin
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  4. N. Gerard
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Buscail, H., Sciora, E., Larpin, J.P. et al. Influence of ceria coatings on growth stresses developed in wüstite scales formed on pure iron at 800°C. Oxid Met 48, 417–438 (1997). https://doi.org/10.1007/BF02153459

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