Abstract
The addition of B2O3 to a Cu/ZnO/Al2O3 catalyst increased the activity of the catalyst for methanol synthesis after an induction period during the reaction. The stability of the B2O3-containing Cu/ZnO/Al2O3 catalyst was greatly improved by the addition of a small amount of colloidal silica to the catalyst.
Similar content being viewed by others
References
K. Klier, Adv. Catal. 31 (1983) 243.
K.C. Waugh, Catal. Today 15 (1992) 51.
I. Wender, Fuel Process. Technol. 48 (1996) 189.
T. Inui, T. Takeguchi, A. Kohama and K. Tanida, Energy Convers. Mgmt 33 (1992) 513.
H. Arakawa, J.-L. Dubois and K. Sayama, Energy Convers. Mgmt 33 (1992) 521.
M. Saito, Catal. Surv. Jpn. 2 (1998) 175.
G.J. Millar, C.H. Rochester and K.C. Waugh, Catal. Lett. 14 (1992) 289.
P.B. Rasmussen, P.M. Holmblad, T. Askgarrda, C.V. Ovesen, P. Stoltze, J.K. Nørskov and I. Chorkendorff, Catal. Lett. 26 (1994) 373.
C. Shao, L. Fan, K. Fujimoto and Y. Iwasawa, Appl. Catal. A 128 (1995) L1.
M. Fujiwara, R. Kiffer, H. Ando and Y. Souma, Appl. Catal. A 121 (1995) 113.
J. Li, X. Zhang and T. Inui, Appl. Catal. A 147 (1996) 87.
I. Gausemel, O.H. Ellestad and C.J. Nielson, Catal. Lett. 45 (1997) 129.
T.C. Schilk, I.A. Fisher and A.T. Bell, Catal. Lett. 54 (1998) 105.
M. Saito, T. Fujitani, M. Takeuchi and T. Watanabe, Appl. Catal. A 138 (1996) 311.
M. Saito, M. Takeuchi, T. Watanabe, J. Toyir, S. Luo and J. Wu, Energy Convers. Mgmt 38 (1997) 403.
J. Wu, S. Luo, J. Toyir, M. Saito, M. Takeuchi and T. Watanabe, Catal. Today 45 (1998) 215.
J. Toyir, M. Saito, I. Yamauchi, S. Luo, J. Wu, I. Takahara and M. Takeuchi, Catal. Today 45 (1998) 245.
K. Ushikoshi, K. Mori, T. Watanabe, M. Takeuchi and M. Saito, in: Studies in Surface Science and Catalysis, Vol. 114, eds. T. Inui, M. Anpo, K. Izui, S. Yanagida and T. Yamaguchi (Elsevier, Amsterdam, 1998) p. 357.
M. Saito, J. Wu, S. Luo, J. Toyir, M. Takeuchi and T. Watanabe, in: Greenhouse Gas Control Technologies, eds. P. Riemer, B. Eliasson and A. Wokaun (Elsevier, Oxford, 1999) p. 337.
K. Mori, K. Ushikoshi, T. Watanabe, M. Takeuchi and M. Saito, in: Greenhouse Gas Control Technologies, eds. P. Riemer, B. Eliasson and A. Wokaun (Elsevier, Oxford, 1999) p. 409.
G.C. Chinchen, C.M. Hay, H.D. Vandervell and K.C. Waugh, J. Catal. 103 (1987) 79.
S. Budavari, The Merck Index, 12th Ed. (Division of Merck Research Laboratories, Merck & Co., 1996) p. 1655.
Author information
Authors and Affiliations
Rights and permissions
About this article
Cite this article
Wu, J., Saito, M. & Mabuse, H. Activity and stability of Cu/ZnO/Al2O3 catalyst promoted with B2O3 for methanol synthesis. Catalysis Letters 68, 55–58 (2000). https://doi.org/10.1023/A:1019010831562
Issue Date:
DOI: https://doi.org/10.1023/A:1019010831562