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On the catalytic C-H activation of some silicon dioxide overlayers on thin metal film systems — An observation on the isokinetic effect

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Abstract

Kinetic data on the exchange reaction betwee hexane and deuterium have recently been reported by Maier and coworkers [1]. The reaction was catalysed by a series of platinum or rhodium systems, some of which had the property that the upper surface was shielded by a silica overlayer. The data are reinterpreted to indicate an isokinetic temperature of 580 K. This observation indicates that all the catalysts behave in a similar manner, which means that the exchange reaction does not require a free metal surface.

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  1. Group of Catalysis Research, Inorganic Chemistry I, Chemical Center, University of Lund, P.O. Box 124, S-221 00, Lund, Sweden

    Ragnar Larsson

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  1. Ragnar Larsson
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Larsson, R. On the catalytic C-H activation of some silicon dioxide overlayers on thin metal film systems — An observation on the isokinetic effect. Catal Lett 10, 317–324 (1991). https://doi.org/10.1007/BF00772086

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  • DOI: https://doi.org/10.1007/BF00772086

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