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New cationic monocarbonyls of manganese(I) with nitriles and isonitriles

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Summary

Monocarbonyls of manganese(I) with two chelating diphosphinestrans-[Mn(CO)(diphos)2(L)]A, [diphos = 1,2-bis(diphenylphosphino)ethane, dppe, or bis(diphenylphosphino)methane, dppm; L=nitriles, NCR (NCMe, NCEt, NCPh, or NCCH2Ph), dinitriles, NCGCN (NCCH2CN, NCCH2CH2CN, oro-(NC)2C6H4), isonitriles, CNR, (CNPh, or CNBut); A = C1O −4 or PF −6 ],trans-[(Mn(CO)(dppm)2)2(μ-NCCH2CH2CN)](ClO4)2 and the monocarbonyl with one diphosphine,mer-[Mn(CO)(dppe)(CNBut)3]ClO4, have been prepared fromtrans-[Mn(CO)(diphos)2Br].

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Authors and Affiliations

  1. Department of Inorganic Chemistry, University of Oviedo, Oviedo, Spain

    Francisco J. Garcia-Alonso & Victor Riera

  2. Department of Inorganic Chemistry, University of Valladolid, Valladolid, Spain

    Maria J. Misas

Authors
  1. Francisco J. Garcia-Alonso
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  2. Victor Riera
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  3. Maria J. Misas
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Additional information

In this paper we have adopted the convention that gives positive shift to signals at higher frequency of ext. H3PO4.

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Garcia-Alonso, F.J., Riera, V. & Misas, M.J. New cationic monocarbonyls of manganese(I) with nitriles and isonitriles. Transition Met Chem 10, 19–21 (1985). https://doi.org/10.1007/BF00620625

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  • DOI: https://doi.org/10.1007/BF00620625

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