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Rate Constant for the Reaction of the OH-Radical with CH2F2

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Abstract

The rate constant value of k 1 = (6.05 ± 0.20)×109 cm3 mol−1 s−1 (with ± 1σ error) has been determined for the reaction OH + CH2F2 (1) by applying the discharge-flow/resonance-fluorescence method at 298 K.

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REFERENCES

  1. D.L. Allbritton, R.T. Watson, P.J. Aucamp (Assement Co-chairs): WMO Global Ozone Research Monitoring Project-Report No. 37. (1994).

  2. C.J. Howard, K.M. Evenson: J. Chem. Phys., 64, 197 (1976).

    Google Scholar 

  3. M.A.A. Clyne, P.M. Holt: J. Chem. Soc. Faraday Trans., 75, 582 (1979).

    Google Scholar 

  4. W.S. Nip, D.L. Singleton, R. Overend, G. Paraskevopoulos: J. Phys. Chem., 83, 2440 (1979).

    Google Scholar 

  5. K.-M. Jeong, F. Kaufman: J. Phys. Chem., 86, 1808 (1982).

    Google Scholar 

  6. R. Talukdar, A. Mellouki, T. Gierczak, J.B. Burkholder, S.A. McKeen, A.R. Ravishankara: J. Phys. Chem., 95, 5815 (1991).

    Google Scholar 

  7. A.M. Schmoltner, R.K. Talukdar, R.F. Warren, A. Mellouki, L. Goldfarb, T. Gierczak, S.A. McKeen, A.R. Ravishankara: J. Phys. Chem, 97, 8976 (1993).

    Google Scholar 

  8. K.-J. Hsu, W.B. DeMore: J. Phys. Chem., 99, 1235 (1995).

    Google Scholar 

  9. R. Atkinson, D.L. Baulch, R. A. Cox, R.F. Hampson, JR., J. A. Kerr, M. J. Rossi, J. Troe: J. Phys. Chem. Ref. Data, 26, 521 (1997).

    Google Scholar 

  10. W.B. DeMore, S.P. Sander, D.M. Golden, R.F. Hampson, M.J. Kurylo, C.J. Howard, A.R. Ravishankara, C.E. Kolb, M.J. Molina: JPL Publication 97-4, Evaluation Number 12, Jet Propulsion Laboratory, California Institute of Technology, Pasadena, CA, 1997.

    Google Scholar 

  11. S. Dóbé, L.A. Khachatryan, T. Bérces: Ber. Bunsenges. Phys. Chem., 93, 847 (1989).

    Google Scholar 

  12. K.H. Hoyermann, in: Physical Chemistry — An Advanced Treatise. Vol. VI. B. Kinetics of Gas Reactions, Chapter 12. Academic Press, New York 1975.

    Google Scholar 

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Authors and Affiliations

  1. Institute of Chemistry, Chemical Research Center, Hungarian Academy of Sciences, Pusztaszeri u. 59-67, H-1025, Budapest, Hungary

    István Szilágyi, Sándor Dóbé & Tibor Bérces

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  1. István Szilágyi
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  2. Sándor Dóbé
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  3. Tibor Bérces
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Szilágyi, I., Dóbé, S. & Bérces, T. Rate Constant for the Reaction of the OH-Radical with CH2F2. Reaction Kinetics and Catalysis Letters 70, 319–324 (2000). https://doi.org/10.1023/A:1010349118536

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