Skip to main content
SpringerLink
Log in

Thermal Analysis and Kinetic Study of Decomposition processes of Some Commercial Pesticides I. Triazine derivatives

  • Published:
Journal of Thermal Analysis and Calorimetry Aims and scope Submit manuscript

Abstract

The thermal behaviour of some commercial pesticides was studied by means of simultaneous TG-DSC measurements. Kinetic parameters relating to liquid—gas-phase transition processes were determined via a dynamic TG technique. Gas chromatography-mass spectrometry were used to make measurements on the gaseous products.

The liquid—gas-phase transition processes of these compounds seem to be influenced by the substituent groups rather than by the side-chains.

A chlorine substituent destabilizes some compounds, bringing closer together the temperatures of melting and liquid—gas-phase transition processes.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. R. White-Stevens, Pesticides in the Environment, Marcel Dekker, New York 1971, Vol. 1, p. 82.

    Google Scholar 

  2. S. Byrdy, K. Gorecki and E. Laszcz, Pesticides, Warsaw 1976, p. 17.

  3. Environmental Health Criteria, No. 9: DDT and its Derivatives, World Health Organization (WHO), Geneva, Switzerland 1979, 33.

  4. A. Jori, Ann. Inst. Super. Sanità, 23 (1987) 147.

    CAS  Google Scholar 

  5. H. Choudhury, J. Coleman, F. L. Mink, C. T. De Rosa and J. F. Stara, Toxicol. Ind. Health, 3 (1987) 5.

    CAS  Google Scholar 

  6. J. Ashby and R. W. Tennant, Mutat. Res., 204 (1988) 17.

    Article  CAS  Google Scholar 

  7. D. K. R. Steward and D. Chisholm, Can. J. Soil. Sci., 61 (1971) 379.

    Article  Google Scholar 

  8. H. V. Morley, Environ. Sci. Res., 10 (1977) 53.

    CAS  Google Scholar 

  9. T. S. S. Dikshith, J. Sci. Ind. Res., 37 (1978) 316.

    CAS  Google Scholar 

  10. P. Michel and A. Abarnou, Bull. Acad. Natl. Med. (Paris) 1967 (1983) 491.

    Google Scholar 

  11. E. W. Bailey and J. L. White, Residue Rev., 32 (1970) 29.

    CAS  Google Scholar 

  12. R. Haque and V. M. Freed, Residue Rev., 52 (1974) 89.

    CAS  Google Scholar 

  13. C. R. Harris, Am. Rev. Entomol., 17 (1972) 112.

    Google Scholar 

  14. M. J. Sanchez-Martin and M. Sanchez-Camazano, Thermochim. Acta, 126 (1988) 319.

    Article  CAS  Google Scholar 

  15. S. A. Taylor and G. I. Ashcroft (Eds), Physical Edaphology, Freeman, San Francisco 1972, p. 396.

    Google Scholar 

  16. J. Lubkowski, T. Taniak, S. Czerminski and J. Blazejowski, Thermochim. Acta, 155 (1989) 7.

    Article  CAS  Google Scholar 

  17. G. Matuschek, K. H. Ohrbach and A. Kettrup, J. Thermal Anal., 39 (1993) 1141.

    CAS  Google Scholar 

  18. H. G. Wiedemann and G. Bayer, Thermochim. Acta, 92 (1985) 399.

    Article  CAS  Google Scholar 

  19. G. Matuschek, K. H. Ohrbach and A. Kettup, Thermochim. Acta, 190 (1991) 111.

    Article  CAS  Google Scholar 

  20. A. Fernández-Alba, I. J. Peréz-Alvarez, J. L. Martínez-Vidal and E. Gonzáles-Prodas, Thermochim. Acta, 211 (1992) 271.

    Article  Google Scholar 

  21. J. Rulewski, J. Rak, P. Dokurno, P. Skurski and J. Blazejowski, J. Thermal Anal., 45 (1995) 839.

    CAS  Google Scholar 

  22. L. Gruzdiewa, P. Dokurno, J. Rak and J. Blazejowski, J. Thermal Anal., 45 (1995) 849.

    CAS  Google Scholar 

  23. F. Rodante, G. Marrosu and G. Catalani, J. Thermal Anal., 38 (1992) 2669.

    Article  CAS  Google Scholar 

  24. E. Knuesely, Pesticide Chemistry in the 20th century, Eds. J. R. Plimmer, American Chemical Society, Washington D.C. 1977, p. 76.

    Google Scholar 

  25. H. O. Esser, G. Depuis, E. Ebert, G. Marco and G. Vogel, Herbicides, Chemistry, Degradation and Mode of Action, Eds. P. C. Kerney and D. D. Kaufman, Dekker, New York 1976, Vol. 1, p. 129.

    Google Scholar 

  26. H. Gysin and E. Knuesely, Advances in pest control research, Eds. R. L. Metcalf, Intescience, 1960, Vol. 3, p. 289.

  27. R. G. Cremlyn, Pesticides, preparation and mode of action, Wiley, Chichester 1978, p. 54.

    Google Scholar 

  28. McCarty and Green, Instruction Manual for the Stanton Redcroft, Simultaneous TG-DSC, January 1989.

  29. C. Plato and A. R. Glasgow Jr., Anal. Chem., 41 (1969) 330.

    Article  CAS  Google Scholar 

  30. C. Plato, Anal. Chem., 44 (1972) 1531.

    Article  CAS  Google Scholar 

  31. J. R. Donnelly, L. A. Drewes, R. L. Johnson, W. P. Munslow, K. K. Knapp and G. W. Sovocool, Thermochim. Acta, 167 (1990) 155.

    Article  CAS  Google Scholar 

  32. G. Rajendran and S. R. Jain, Thermochim. Acta, 82 (1984) 319.

    Article  Google Scholar 

  33. F. Rodante, G. Marrosu and G. Catalani, Thermochim. Acta, 194 (1992) 192.

    Article  Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Dipartimento di Ingegneria Chimica, dei Materiali, delle Materie Prime e Metallurgia, Universitá di Roma "La Sapienza", Via del Castro Laurenziano 7, 00161, Roma

    F. Rodante

  2. Istituto Regina Elena, Viale Regina Elena 293, Roma

    G. Catalani

  3. Presidio Multizonale di Prevenzione, Via Salaria per l'Aquila 8, Rieti, Italy

    M. Guidotti

Authors
  1. F. Rodante
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. G. Catalani
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. M. Guidotti
    View author publications

    You can also search for this author in PubMed Google Scholar

Rights and permissions

Reprints and permissions

About this article

Cite this article

Rodante, F., Catalani, G. & Guidotti, M. Thermal Analysis and Kinetic Study of Decomposition processes of Some Commercial Pesticides I. Triazine derivatives. Journal of Thermal Analysis and Calorimetry 53, 937–956 (1998). https://doi.org/10.1023/A:1010198621609

Download citation

  • Issue Date:

  • DOI: https://doi.org/10.1023/A:1010198621609

Search

Navigation