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Characterization of zirconium, lanthanum and lead oxide deposits prepared by cathodic electrosynthesis

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Abstract

Cathodic electrosynthesis of zirconium, lanthanum and lead oxides was performed from aqueous solutions of ZrOCl2 · 8H2O, La(NO3)3 · 6H2O and Pb(NO3)2, respectively. The deposits were characterized by X-ray diffraction, thermogravimetric and differential thermal analyses. Crystallite sizes of zirconia were derived at different temperatures from X-ray broadening data. The influence of hydrogen peroxide on the electrosynthesis process, crystallization and phase evolution of deposits has been studied. A possible mechanism of electrosynthesis and the role of hydrogen peroxide are discussed.

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Authors and Affiliations

  1. Israel Institute of Metals, Technion-Israel Institute of Technology, Haifa, 32000, Israel

    I. Zhitomirsky & L. Gal-Or

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  1. I. Zhitomirsky
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  2. L. Gal-Or
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Zhitomirsky, I., Gal-Or, L. Characterization of zirconium, lanthanum and lead oxide deposits prepared by cathodic electrosynthesis. Journal of Materials Science 33, 699–705 (1998). https://doi.org/10.1023/A:1004389712291

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