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Investigation of SbCl5-donor complexes with charge transfer by the NQR method

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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    The NQR-121Sb and123Sb spectra of two complexes and35Cl spectra of six complexes of antimony pentachloride were investigated.

  2. 2.

    The degree of charge transfer and the distribution of charge in the acceptor molecule was calculated according to the Daily-Townes theory.

  3. 3.

    The influence of electronic and steric factors on the NQR-35Cl spectra was investigated.

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Authors and Affiliations

  1. Siberian Branch of the Academy of Sciences of the USSR, Institute of Petroleum Chemistry, Tomsk

    O. Kh. Poleshchuk, Yu. K. Maksyutin & I. G. Orlov

Authors
  1. O. Kh. Poleshchuk
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  2. Yu. K. Maksyutin
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  3. I. G. Orlov
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Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 1, pp. 109–113, January, 1974.

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Poleshchuk, O.K., Maksyutin, Y.K. & Orlov, I.G. Investigation of SbCl5-donor complexes with charge transfer by the NQR method. Russ Chem Bull 23, 101–104 (1974). https://doi.org/10.1007/BF00922322

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  • DOI: https://doi.org/10.1007/BF00922322

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