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1H-NMR-spektroskopische Analyse von 2-Chlor-1.3.2-dioxarsolan

1 H-NMR-spectroscopic analysis of 2-chloro-1.3.2-dioxarsolane

  • Organische Chemie und Biochemie
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Monatshefte für Chemie / Chemical Monthly Aims and scope Submit manuscript

Abstract

The1H-NMR-spectral data of 2-chloro-1.3.2-dioxarsolane are presented and discussed. The protons of the methylene groups form in concentrated solutions by rapide chlorine exchange anAA′A″A‴ spin system. In dilute solutions the protons form anAA′BB′ spin system, which is changed to anAA′A″A‴ system by addition of chlorine ions.

The vicinal H−C−C−H-coupling constants indicate a twist-envelope conformation.

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Literatur

  1. O. Adler undF. Kober, Z. Anorg. Allg. Chem.420, 177 (1976); Z. Naturforsch.31 b, 304, 472 (1976); Org. Mass Spectrom.11, 40 (1976);F. Kober, W. J. Rühl undL. Zimmer, Chem. Ber.109, 493 (1976);F. Kober undW. J. Rühl, J. organometal. Chem.101, 57 (1975); Z. Naturforsch.31 b, 190 (1976);F. Kober, Z. Chem.16, 159 (1976).

    Google Scholar 

  2. D. W. Aksnes undO. Vikane, Acta Chem. Scand.27, 1337 (1973).

    Google Scholar 

  3. J. P. Casey undK. Mislow, Chem. Commun.1970, 999 (1970);G. H. Senkler undK. Mislow, J. Amer. Chem. Soc.94, 291 (1972);A. Rank, L. C. Allen undK. Mislow, Angew. Chem.82, 453 (1970);R. D. Baechler, P. P. Caesey, R. J. Cook, G. H. Senkler undK. Mislow, J. Amer. Chem. Soc.94, 2859 (1972);J. A. Andose, A. Rank undK. Mislow, J. Amer. Chem. Soc.96, 6904 (1974);R. E. Weston, J. Amer. Chem. Soc.76, 2645 (1954).

  4. P. Haake, J. P. McNeal undE. J. Goldsmith, J. Amer. Chem. Soc.90, 715 (1968);S. C. Peake, M. Field, R. Schmutzler, R. K. Harris, J. M. Nickols undR. G. Rees, J. Chem. Soc.1972, 380 (1972);K. Berges, M. Bjorøy undT. Gramstad, Acta Chem. Scand.26, 2156, 3037 (1972);D. Aksnes undO. Vikane, Acta Chem. Scand.26, 1532 (1972);27, 2135 (1973).

    Google Scholar 

  5. G. Kamai undZ. L. Khisamova, Dokl. Akad. Nauk SSSR76, 535 (1971).

    Google Scholar 

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Authors and Affiliations

  1. Fachbereich 8, Technische Hochschule Darmstadt (E. Zintl-Institut), Hochschulstraße 4, D-6100, Darmstadt, Bundesrepublik Deutschland

    Oswald Adler &  Friedhelm Kober

Authors
  1. Oswald Adler
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  2. Friedhelm Kober
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Adler, O., Kober, F. 1H-NMR-spektroskopische Analyse von 2-Chlor-1.3.2-dioxarsolan. Monatshefte für Chemie 108, 65–68 (1977). https://doi.org/10.1007/BF00900908

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  • DOI: https://doi.org/10.1007/BF00900908

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