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  • 1
    Publication Date: 2021-10-29
    Description: Recognition of any intra-oceanic arc-trench system (IOAS) could provide invaluable information on the tectonic framework and geodynamic evolution of the vanished ocean basin. The Tanjianshan Complex and mafic-ultramafic rocks along the North Qaidam ultra-high pressure metamorphic belt in NW China record the subduction process of the Proto-Tethyan Ocean. Four lithotectonic units, including island arc, ophiolite, forearc basin, and accretionary complex, are recognized based on detailed field investigation. They rest on the northern margin of the Qaidam block and occur as allochthons in fault contact with underlying high-grade metamorphic rocks. The ophiolite unit mainly consists of ultramafic rocks, 527−506 Ma gabbro, 515−506 Ma plagiogranite, dolerite, and massive lava. High-Cr spinels in serpentinite, dolerite with forearc basalt affinity, and boninitic lava collectively indicate a forearc setting. The accretionary complex, exposed to the south of the ophiolite complex and island arc, is highly disrupted and contains repeated slices of basalt, 495−486 Ma tuff, chert, limestone, and mélange. Tuffs with positive zircon εHf(t) values indicate derivation from a nearby juvenile island arc. These lithotectonic units, as well as the back-arc basin, are interpreted to constitute a Cambrian IOAS that formed during the northward subduction of the Proto-Tethyan Ocean. Combined with regional geology, we propose a new geodynamic model involving short-lived Mariana-type subduction and prolonged Andean-type subduction to account for the complex evolution of the Proto-Tethyan Ocean. The reconstruction of a relatively complete IOAS from the North Qaidam belt not only reveals a systematic evolution of intra-oceanic subduction but also advances our understanding of the subduction and accretion history of the Proto-Tethyan Ocean.
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  • 2
    Publication Date: 2021-10-27
    Description: Granitoids with diverse composition and tectonic settings provide important tools for exploring crustal evolution and regional geodynamic history. Here we present an integrated study using petrological, mineralogical, zircon U-Pb geochronological, whole-rock geochemical, and isotopic data on the Late Triassic Daocheng batholith in the Yidun Terrane with a view to understanding the petrogenesis of a compositionally diverse batholith and its implications for the evolution of the Paleo-Tethys Ocean in the eastern Tibetan Plateau. The different lithological units of the batholith, including granodiorite, monzogranite, and quartz diorite, with abundant mafic microgranular enclaves in the granodiorite (MME I) and monzogranite (MME II), show identical crystallization ages of 218−215 Ma. The mineral assemblage and chemical composition of the granodiorite are identical to those of tonalitic-granodioritic melts generated under water-unsaturated conditions. The insignificant Eu anomalies and low magmatic temperatures indicate hydrous melting in the source. The relatively narrow range of whole-rock chemical and Sr-Nd isotopes, as well as the zircon trace element and Hf isotopic compositions of the granodiorite, suggest a homogeneous crustal source for the magma. Our modeling suggests that the rock was produced by 20−50% of lower crustal melting. The Daocheng monzogranites display more evolved compositions and larger variations in Sr-Nd-Hf isotopes than the granodiorite, which are attributed to assimilation and the fractional crystallization process. This is evidenced by the presence of metasedimentary enclave and inherited zircon grains with Neoproterozoic and Paleozoic ages, a non-cotectic trend in composition, and the trend shown by the modeling of initial 87Sr/86Sr ratios and Sr. The quartz diorites and MMEs showing composition similar to that of andesitic primary magma have high zircon εHf(t) values and are characterized by enrichment in LILEs and depletion of HFSEs. They were derived from the partial melting of lithospheric mantle that had been metasomatized by slab melts and fluids. The MMEs in both rocks display typical igneous texture and higher rare earth element (REE) and incompatible element concentrations than their host granites. The presence of fine-grained margins, acicular apatite, and plagioclase megacrysts suggests a magma mingling process. The overgrowth of amphibole around the pyroxene, quartz ocelli rimmed by biotite, and oscillatory zones of plagioclase are all indicative of chemical diffusion. Their enriched Sr-Nd isotopes imply isotopic equilibrium with the host granites. Based on a comparison with the coeval subduction-related magmatism, we propose that subduction and subsequent rollback of the Paleo-Tethys (Garzê-Litang Ocean) oceanic slab was the possible mechanism that triggered the diverse Triassic magmatism within the eastern Tibetan Plateau.
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  • 3
    Publication Date: 2021-09-23
    Description: Bulk rock geochemistry and sensitive high-resolution ion microprobe zircon geochronology of igneous and metaigneous rocks of the Évora gneiss dome, located to the north of the reworked Rheic Ocean suture zone in the southwest Iberian Variscan belt, reveal a succession of magmatic and melting events lasting ∼30 m.y. between ca. 341−314 Ma. The study of detailed field relationships of orthomigmatites (i.e., migmatites from igneous protoliths) and host granitic rocks proved to be crucial to reconstruct the complex sequence of tectono-thermal events of the Évora gneiss dome. The older igneous protoliths, with marked geochemical arc-like signatures, are represented by 338 ± 3 Ma tonalites and 336 ± 3 Ma diorites. These tonalites and diorites appear as mesosomes of igneous orthomigmatites containing new melts (leucosomes) of monzogranite composition and silica-poor trondhjemites formed in a melting episode at 329 ± 4/6 to 327 ± 3 Ma. The absence of peritectic phases (e.g., pyroxene), together with shearing associated with migmatization, imply the existence of water-rich fluids during melting of the older igneous rocks of the Évora gneiss dome. This melting event is coeval with the second magmatic event of the Évora gneiss dome represented by the neighboring Pavia pluton. A porphyritic monzogranite dated at 314 ± 4 Ma defines a later magmatic event. The porphyritic monzogranite encloses large blocks of the orthomigmatites and contains magmatic mafic enclaves (autoliths) dated at 337 ± 4 Ma that are ∼23 m.y. older than the host rock. All studied rocks of the Évora gneiss dome show arc-like, calc-alkaline geochemical signatures. Our results support recycling of intermediate-mafic plutonic rocks, representing the root of an early magmatic arc that formed at the time of Gondwana-Laurussia convergence (after the closure of the Rheic Ocean) and coeval subduction of the Paleotethys. A geodynamic model involving ridge subduction is proposed to explain the Early Carboniferous intra-orogenic crustal extension, dome formation, exhumation of high-grade rocks, compositional variations of magmatism and formation of new granitic magmatism in which, arc-like signatures were inherited from the crustal source.
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  • 4
    Publication Date: 2021-09-22
    Description: The Xiong’ershan district in central China hosts broadly coeval porphyry Au (Qiyugou deposit), porphyry Mo (Leimengou deposit), and barren (Huashan pluton) systems. The key controls on the ore potential and different mineralization styles in these systems are not well understood, with first-order differences in fluid chemistry and melt sources being the main alternatives. The fluid inclusion characteristics of all three porphyry systems have been studied using an integrated approach that combines field geology, petrography, microthermometry, and laser ablation−inductively coupled plasma−mass spectrometry analysis of single fluid inclusions. The results permit a reconstruction of the magmatic-hydrothermal evolution of the ore-forming fluids, and to elucidate whether specialized hydrothermal fluids strongly enriched in ore metals (i.e., Mo, Au, Cu) were essential to form the economically significant deposits. The fluid compositions across the three hydrothermal stages from the Qiyugou Au deposit remain approximately the same over time, suggesting that progressive magma fractionation, fluid-rock reaction along fluid path, and mineral precipitation had a limited effect on fluid composition. The syn-ore stage fluids of the Leimengou Mo deposit are characterized by higher Cs/Na, Sr/Na, and B/Na, but lower K/Na and Cl/Na ratios, and also have salinities and homogenization temperatures distinct from the earlier fluids. This demonstrates that Mo mineralization was caused by a second pulse of fluid input from a highly fractionated felsic magma subsequent to the pre-ore stage. At the Huashan barren pluton, fluids from phase II have higher Cs/Na, B/Na, Li/Na, and Rb/Na ratios with lower homogenization temperatures than fluids occurring in porphyritic rocks of phase III, reflecting a higher degree of magma fractionation of this plutonic complex. The Huashan pluton does not host economic mineralization which is likely caused by the low ore metal tenor, inefficient fluid extraction from the melt, or the flat-roof geometry preventing accumulation of a large volume of fluid in the apical part. The Au tenor of the Qiyugou deposit was most likely contributed by mantle-derived material of higher Mg/Na, Fe/Na, Pb/Na, and Zn/Na ratios. Taken together, the metal charged magmatic-hydrothermal fluids, steeply dipping geometry, and small volume of the porphyry stocks all suggest that a much larger magma chamber feeding the porphyry systems should be present at deeper levels with good potential for Mo mineralization below the current level of exposure at Qiyugou deposit.
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  • 5
    Publication Date: 2021-09-21
    Description: The paleogeographic position of the central Dodecanese Islands at the transition between the Aegean and Anatolian plates plays a considerable role in understanding the link between both geologically unique domains. In this study, we investigate the tectonic history of the central Dodecanese Islands and the general correlation with the Aegean and western Anatolian and focus on the poorly studied islands of Kalymnos and Telendos. Three different major tectonic units were mapped on both islands from bottom to top: (1) The Kefala Unit consists of late Paleozoic, fossil-rich limestones, which have been deformed into a SE-vergent fold-and-thrust belt sealed by an up to 200-m-thick wildflysch-type olistostrome with marble and ultramafic blocks on a scale of tens of meters. (2) The Marina Basement Unit consists of a Variscan amphibolite facies basement with garnet mica schists, quartzites, and amphibolites. (3) Verrucano-type formation violet shales and Mesozoic unmetamorphosed limestones form the Marina Cover Unit. Correlation of these units with other units in the Aegean suggests that Kalymnos is paleogeographically located at the southern margin of the Pelagonian domain, and therefore it was in a structurally upper tectonic position during the Paleogene Alpine orogeny. New white mica 40Ar/39Ar ages confirm the Carboniferous deformation of the Marina Basement Unit followed by a weak Triassic thermal event. Single-grain white mica 40Ar/39Ar ages from pressure solution cleavage of the newly defined Telendos Thrust suggest that the Marina Basement Unit was thrusted toward the north on top of the Kefala Unit in the Paleocene. Located at a tectonically upper position, the units exposed in the central Dodecanese escaped subduction and the syn-orogenic, high-pressure metamorphism. However, these units were affected by post-orogenic extension, and the contact between the Marina Basement Unit and the non-metamorphic Marina Cover Unit has been reactivated by the cataclastic top-to-SSW, low-angle Kalymnos Detachment. Zircon (U-Th)/He ages from the Kefala and Marina Basement Units are ca. 30 Ma, which indicates that exhumation and cooling below the Kalymnos Detachment started in the Oligocene. Conjugate brittle high-angle normal fault systems, which resulted in the formation of four major WNW-ESE−trending graben systems on Kalymnos, localized mainly in the Marina Cover Unit and probably rooted in the mechanically linked Kalymnos Detachment. Since Oligo-Miocene deformation in the northern Dodecanese records top-to-NNE extension and the Kalymnos Detachment accommodated top-to-SSW extension, we suggest that back-arc extension in the whole Aegean realm and transition to the Anatolian plate is bivergent.
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  • 6
    Publication Date: 2021-09-21
    Description: During Deep Sea Drilling Project (DSDP) Leg 21, Cenozoic and latest Cretaceous sediments were recovered at Site 208 on the Lord Howe Rise, Southwest Pacific. We provide new biostratigraphic, magnetostratigraphic and chemostratigraphic data from Site 208 to constrain the stratigraphy around the Cretaceous-Paleogene (K-Pg) boundary and to determine the depth of the K-Pg boundary more precisely. Biostratigraphic data from calcareous nannofossils indicate a near-continuous succession of sediments from the mid-Maastrichtian (Late Cretaceous) to lowermost Thanetian (Paleocene) at depths of 540−590 m below seafloor (mbsf). The biostratigraphic data suggest that the K-Pg boundary corresponds to a siliceous claystone at the base of an interval of silicified sediments (576.0−576.8 mbsf). Carbonate carbon isotopic composition (δ13Ccarb) reveals a negative shift across this interval, which is consistent with global patterns of δ13C across the K-Pg boundary. Osmium concentration and Os isotopic composition (187Os/188Os) can also be used to identify the K-Pg boundary interval, as it is marked by a peak in Os concentration and a drop in 187Os/188Os values to 0.12−0.15, both of which are the result of the Chicxulub impact event. Our 187Os/188Os data show trends similar to those of coeval global seawater with the lowest value of 0.12−0.16 in the siliceous claystone (576.8 mbsf). However, the concentration of Os is low (
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  • 7
    Publication Date: 2021-09-20
    Description: To the memory of Nicholas John (Nick) Archibald (1951−2014), master of cratonic geology. Cratons, defined by their resistance to deformation, are guardians of crustal and lithospheric material over billion-year time scales. Archean and Proterozoic rocks can be found in many places on earth, but not all of them represent cratonic areas. Some of these old terrains, inappropriately termed “cratons” by some, have been parts of mobile belts and have experienced widespread deformations in response to mantle-plume-generated thermal weakening, uplift and consequent extension and/or various plate boundary deformations well into the Phanerozoic. It is a common misconception that cratons consist only of metamorphosed crystalline rocks at their surface, as shown by the indiscriminate designation of them by many as “shields.” Our compilation shows that this conviction is not completely true. Some recent models argue that craton formation results from crustal thickening caused by shortening and subsequent removal of the upper crust by erosion. This process would expose a high-grade metamorphic crust at the surface, but greenschist-grade metamorphic rocks and even unmetamorphosed supracrustal sedimentary rocks are widespread on some cratonic surfaces today, showing that craton formation does not require total removal of the upper crust. Instead, the granulitization of the roots of arcs may have been responsible for weighing down the collided and thickened pieces and keeping their top surfaces usually near sea level. In this study, we review the nature and origin of cratons on four well-studied examples. The Superior Province (the Canadian Shield), the Barberton Mountain (Kaapvaal province, South Africa), and the Yilgarn province (Western Australia) show the diversity of rocks with different origin and metamorphic degree at their surface. These fairly extensive examples are chosen because they are typical. It would have been impractical to review the entire extant cratonic surfaces on earth today. We chose the inappropriately named North China “Craton” to discuss the requirements to be classified as a craton.
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  • 8
    Publication Date: 2021-09-20
    Description: During the collision of India and Eurasia, regional-scale strike-slip shear zones played a key role in accommodating lateral extrusion of blocks, block rotation, and vertical exhumation of metamorphic rocks as presented by deformation on the Ailao Shan-Red River shear zone (ARSZ) in the Eastern Himalayan Syntaxis region and western Yunnan, China. We report structural, mica Ar/Ar, apatite fission-track (AFT), and apatite (U-Th)/He (AHe) data from the Diancangshan massif in the middle segment of the ARSZ. These structural data reveal that the massif forms a region-scale antiform, bordered by two branches of the ARSZ along its eastern and western margins. Structural evidence for partial melting in the horizontal mylonites in the gneiss core document that the gneiss experienced a horizontal shear deformation in the middle crust. Muscovite Ar/Ar ages of 36−29 Ma from the core represent cooling ages. Muscovite Ar/Ar ages of 25 and 17 Ma from greenschist-facies mylonites along the western and southern shear zones, respectively, are interpreted as recording deformation in the ARSZ. The AFT ages, ranging from 15 to 5 Ma, represent a quiescent gap with a slow cooling/exhumation in the massif. AHe results suggest that a rapid cooling and final exhumation episode of the massif could have started before 3.2 Ma, or likely ca. 5 Ma, and continue to the present. The high-temperature horizontal shearing layers of the core were first formed across the Indochina Block, locally antiformed along the tectonic boundaries, and then cooled through the mica Ar-Ar closure temperature during Eocene or early Oligocene, subsequently reworked and further exhumed by sinistral strike-slip movement along the ARSZ during the early Oligocene (ca. 29 Ma), lasting until ca. 17 Ma, then final exhumation of the massif occurred by dextral normal faulting on the Weixi-Qiaohou and Red River faults along the limbs of the ARSZ since ca. 5 Ma. The formation of the antiform could indicate local crustal thickening in an early transpressional setting corresponding to India-Asia convergence. Large-scale sinistral ductile shear along the ARSZ in the shallow crust accommodated lateral extrusion of the Indochina Block, and further contributed to the vertical exhumation of the metamorphic massif from the late Oligocene to the middle Miocene. Furthermore, the change of kinematic reversal and associated cooling episodes along the ARSZ since the middle Miocene or early Pliocene imply a tectonic transfer from strain localization along the major tectonic boundaries to continuous deformation corresponding to plateau growth and expansion.
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  • 9
    Publication Date: 2021-09-20
    Description: Spinel peridotite xenoliths (one plagioclase-bearing) hosted in alkaline basalts from Tallante (southeast Spain) record the mineralogical and geochemical fingerprint of the subcontinental lithospheric mantle (SCLM) evolution beneath the southern Iberian margin. Mantle metasomatism in fertile lherzolites caused the crystallization of clinopyroxene + orthopyroxene + spinel clusters through the percolation of Miocene subalkaline melts during the westward migration of the subduction front in the western Mediterranean. In the Pliocene, heat and volatiles provided by alkaline host-magmas triggered very low melting degrees of metasomatic pyroxene-spinel assemblages, producing melt quenched to silicate glass and reactive spongy coronae around clinopyroxene and spinel. Refertilization of the Tallante peridotites induced the precipitation of base-metal sulfides (BMS) included in metasomatic clino- and orthopyroxene. These sulfides consist of pentlandite ± chalcopyrite ± bornite aggregates with homogeneous composition in terms of major elements (Ni, Fe, Cu) and semi-metals (Se, As, Te, Sb, Bi), but with wide variability of platinum-group elements (PGE) fractionation (0.14 〈 PdN/IrN 〈 30.74). Heterogeneous PGE signatures, as well as the presence of euhedral Pt-Pd-Sn-rich platinum-group minerals (PGM) and/or Au-particles within BMS, cannot be explained by conventional models of chalcophile partitioning from sulfide melt. Alternatively, we suggest that they reflect the incorporation of distinct populations of BMS, PGM, and metal nanoparticles (especially of Pt, Pd, and Au) during mantle melting and/or melt percolation. Therefore, we conclude that Miocene subalkaline melts released by asthenosphere upwelling upon slab tearing of the Iberian continental margin effectively stored metals in metasomatized domains of this sector of the SCLM. Remarkably high Au concentrations in Tallante BMS (median 1.78 ppm) support that these metasomatized domains provided a fertile source of metals, especially gold, for the ore-productive Miocene magmatism of the westernmost Mediterranean.
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  • 10
    Publication Date: 2021-09-17
    Description: New trace-element, radiogenic Sr-Nd-Pb isotopic and geochronological data from Middle-Late Cretaceous Zagros ophiolites of Iran give new insights into the tectono-magmatic history of these supra-subduction zone (SSZ)-type ophiolites. The distribution of Middle-Late Cretaceous SSZ-type ophiolites in Iran comprises two parallel belts: (1) the outer Zagros ophiolitic belt and (2) the inner Zagros ophiolitic belt. These Middle-Late Cretaceous ophiolites were generated by seafloor spreading in what became the fore-arc and back-arc during the subduction initiation event and now define a ∼3000-km-long belt from Cyprus to Turkey, Syria, Iran, the UAE, and Oman. The Zagros ophiolites contain complete (if disrupted) mantle and crustal sequences. Mantle sequences from both outer-belt and inner-belt ophiolites are dominated by dunites, harzburgites, and lherzolites with minor chromitite lenses. Peridotites are also intruded by gabbros and a variety of mafic to minor felsic (plagiogranite and dacite) dikes. Crustal rocks comprise ultramafic-mafic cumulates as well as isotropic gabbros, sheeted dike complexes, pillowed and massive lavas, and felsic rocks. Our new zircon U-Pb ages indicate that the outer-belt and inner-belt ophiolites formed near coevally during the Middle-Late Cretaceous; 100−96 Ma for the outer belt and 105−94 Ma for the inner belt. Both incompatible-element ratios and isotopic data confirm that depleted mantle and variable contributions of subduction components were involved in the genesis of outer-belt and inner-belt rocks. Our data for the outer belt and inner belt along with those from better-studied ophiolites in Cyprus, Turkey, the UAE, and Oman lead to the conclusion that a broad, ∼3000-km-long swath of fore-arc lithosphere was created during Middle-Late Cretaceous time.
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