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  • 1
    Electronic Resource
    Electronic Resource
    [s.l.] : Nature Publishing Group
    Nature 319 (1986), S. 314-316 
    ISSN: 1476-4687
    Source: Nature Archives 1869 - 2009
    Topics: Biology , Chemistry and Pharmacology , Medicine , Natural Sciences in General , Physics
    Notes: [Auszug] The four isoleucine stereoisomers are shown in Fig. 1 as are their interconversion pathways by epimerization at the a- and -carbons. The a-epimerization rates of D-Ile and L-alle would be expected to be similar to those of the diastereomeric pair L-Ile and D-alle. Interconversion of the enantiomers ...
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    [s.l.] : Nature Publishing Group
    Nature 339 (1989), S. 463-465 
    ISSN: 1476-4687
    Source: Nature Archives 1869 - 2009
    Topics: Biology , Chemistry and Pharmacology , Medicine , Natural Sciences in General , Physics
    Notes: [Auszug] In order for an organic cosmochemical signal to be detectable in K/T boundary sediments, the organic compounds in the bolide must be unique so that they can be differentiated from terrestrial organic molecules, and some finite fraction of these compounds must escape decomposition during the impact ...
    Type of Medium: Electronic Resource
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  • 3
    Electronic Resource
    Electronic Resource
    Springer
    Origins of life and evolution of the biospheres 25 (1995), S. 111-118 
    ISSN: 1573-0875
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology , Geosciences
    Notes: Abstract It has been postulated that amino acid stability at hydrothermal vent temperatures is controlled by a metastable thermodynamic equilibrium rather than by kinetics. Experiments reported here demonstrate that the amino acids are irreversibly destroyed by heating at 240 °C and that quasi-equilibrium calculations give misleading descriptions of the experimental observations. Equilibrium thermodynamic calculations are not applicable to organic compounds under high-temperature submarine vent conditions.
    Type of Medium: Electronic Resource
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  • 4
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    PANGAEA
    In:  Supplement to: Chapman, Mark R; Shackleton, Nicholas J; Zhao, Meixun; Eglinton, Geoffrey (1996): Faunal and alkenone reconstructions of subtropical North Atlantic surface hydrography and paleotemperature over the last 28 kyr. Paleoceanography, 11(3), 343-358, https://doi.org/10.1029/96PA00041
    Publication Date: 2023-05-12
    Description: Two techniques for estimating past variations in sea surface temperature (SST) have been used to investigate climatic change in Biogeochemical Oceanic Flux Study (BOFS) core 31K (19°N, 20°W) from the eastern subtropical Atlantic. High-resolution SST records for the last 28 kyr have been produced using planktonic foraminiferal assemblages, based on the Imbrie-Kipp transfer function technique, and the UK' 37 index derived from abundances of C37 alkenones biosynthesized by prymnesiophyte algae. Modern observations suggest that these indices reflect particular hydrographic conditions in the upper ocean: the UK? 37 index corresponds to the temperature at the time of maximum coccolith productivity, typically late spring-early summer in the study area today, whereas the faunal transfer function is calibrated for seasonal maximum and minimum temperatures. In general, the faunal and biomarker paleotemperature records display comparable SST variations during the last glacial and deglacial, but although the overall trends are similar, differences exist in the magnitude and timing of these temperature changes. Most notably, the faunal T warm and UK' 37 SST estimates diverge by 3°C between 8 ka and 6 ka, and this offset persists through the late Holocene. This difference cannot be adequately explained by uncertainties associated with either the calibration data sets or fluctuating preservation levels. We therefore propose that the deviation in SST estimates is linked to a switch in the seasonal timing of maximum coccolith production from the summer in the glacial ocean to the late spring-early summer in the modern ocean. Our results suggest that a dual approach to SST estimation based on faunal and biomarker proxies can provide a valuable means of evaluating mixed layer and productivity changes associated with the movement of oceanographic frontal zones during the late Quaternary.
    Keywords: AGE; Biogeochemical Ocean Flux Study; BOFS; BOFS31/1K; BOFS31#1; Calculated from UK'37 (Prahl et al., 1988); CD53; Charles Darwin; DEPTH, sediment/rock; GLAMAP; Globigerina bulloides, δ18O; KAL; Kasten corer; Mass spectrometer VG Isogas Prism; Northeast Atlantic; Sea surface temperature, annual mean; Sea surface temperature, summer; Sea surface temperature, winter; Transfer function (Imbrie & Kipp, 1971, in Turekian, Yale Univ Press)
    Type: Dataset
    Format: text/tab-separated-values, 210 data points
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  • 5
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    PANGAEA
    In:  Supplement to: Coppola, Alysha I; Wiedemeier, Daniel B; Galy, Valier; Haghipour, Negar; Hanke, Ulrich M; Nascimento, Gabriela S; Usman, Muhammed Ojoshogu; Blattmann, Thomas Michael; Reisser, Moritz; Freymond, Chantal V; Zhao, Meixun; Voss, Britta; Wacker, Lukas; Schefuß, Enno; Peucker-Ehrenbrink, Bernhard; Abiven, Samuel; Schmidt, Michael W I; Eglinton, Timothy Ian (2018): Global-scale evidence for the refractory nature of riverine black carbon. Nature Geoscience, 11(8), 584-588, https://doi.org/10.1038/s41561-018-0159-8
    Publication Date: 2023-01-13
    Description: Wildfires and incomplete combustion of fossil fuel produce large amounts of black carbon. Black carbon production and transport are essential components of the carbon cycle. Constraining estimates of black carbon exported from land to ocean is critical, given ongoing changes in land use and climate, which affect fire occurrence and black carbon dynamics. Here, we present an inventory of the concentration and radiocarbon content (∆14C) of particulate black carbon for 18 rivers around the globe. We find that particulate black carbon accounts for about 15.8 ± 0.9% of river particulate organic carbon, and that fluxes of particulate black carbon co-vary with river-suspended sediment, indicating that particulate black carbon export is primarily controlled by erosion. River particulate black carbon is not exclusively from modern sources but is also aged in intermediate terrestrial carbon pools in several high-latitude rivers, with ages of up to 17,000 14C years. The flux-weighted 14C average age of particulate black carbon exported to oceans is 3,700 ± 400 14C years. We estimate that the annual global flux of particulate black carbon to the ocean is 0.017 to 0.037 Pg, accounting for 4 to 32% of the annually produced black carbon. When buried in marine sediments, particulate black carbon is sequestered to form a long-term sink for CO2.
    Type: Dataset
    Format: application/vnd.openxmlformats-officedocument.spreadsheetml.sheet, 29.3 kBytes
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  • 6
    Publication Date: 2023-04-28
    Keywords: Age model; Age model in radiocarbon 14C ages; Alkenone, unsaturation index UK37; Alkenone per unit sediment mass; Biogeochemical Ocean Flux Study; BOFS; BOFS31/1K; BOFS31#1; Calculated from C37 alkenones (Brassell et al., 1986); Calculated from UK'37 (Prahl et al., 1988); CD53; Charles Darwin; DEPTH, sediment/rock; Gas chromatography; KAL; Kasten corer; Northeast Atlantic; Sea surface temperature, annual mean
    Type: Dataset
    Format: text/tab-separated-values, 494 data points
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  • 7
    Publication Date: 2023-05-20
    Description: Sediment cores at three locations were collected using a push corer by diving and a Vibecore-D corer on the research vessel RV Solander of Australian Institute of Marine Science in 2011, 2013 and 2014. The concentration profiles of 210Pb were determined through the measurement of 210Po in radioactive equilibrium at Edith Cowan University. The concentrations of 137Cs were determined by gamma-ray spectrometry (Canberra Be3830) with a relative counting efficiency of 35% and an energy resolution of 1.8 keV (at 1332 keV). Grain sizes were measured using a Malvern Mastersizer 2000F Laser Particle Sizer, after pretreated with 10% H2O2, 10% HCl and 0.05% (NaPO3)6 solution. The sterol contents were determined by GC (Agilent 7890 A) with an FID detector and a HP-1 column (50 m × 0.32 μm × 0.17 μm).
    Type: Dataset
    Format: application/zip, 10 datasets
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  • 8
    Publication Date: 2023-05-20
    Keywords: Age; AGE; COMPCORE; Composite Core; Kimberley_coast_sediments; Principal component 1; Principal component 2
    Type: Dataset
    Format: text/tab-separated-values, 57 data points
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  • 9
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    PANGAEA
    In:  Supplement to: Chen, Mengna; Bi, Rong; Chen, Xi; Ding, Yang; Zhang, Hailong; Li, Li; Zhao, Meixun (2019): Stoichiometric and sterol responses of dinoflagellates to changes in temperature, nutrient supply and growth phase. Algal Research, 42, 101609, https://doi.org/10.1016/j.algal.2019.101609
    Publication Date: 2023-06-19
    Description: We investigated the responses of elemental stoichiometry (POC, PON) and sterol contents (brassicasterol, dinosterol) in three dinoflagellate species (Prorocentrum donghaiense, Prorocentrum minimum and Karenia mikimotoi) to changes in temperatures (15, 20 and 25 °C), N:P supply ratios (molar ratios 10:1, 24:1 and 63:1) in the exponential phase in batch culture experiments.
    Keywords: 24-Methylcholesta-5,22E-dien-3beta-ol per cell; 4alpha,23,24-Trimethyl-5alpha-cholest-22E-en-3beta-ol per cell; Carbon; Dinoflagellates; nitrogen; Nitrogen, organic, particulate/Carbon, organic, particulate ratio; Particulate organic carbon production per cell; Particulate organic nitrogen production per cell; Ratio; Species; sterols; Temperature, technical; Treatment; warming
    Type: Dataset
    Format: text/tab-separated-values, 800 data points
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  • 10
    Publication Date: 2023-06-27
    Keywords: CALYPSO; Calypso Corer; Carbon, inorganic, total; Carbon, organic, total; Carbon, total; DEPTH, sediment/rock; Element analyser CHN; Element analysis coulometric; IMAGES; IMAGES III - IPHIS; International Marine Global Change Study; Marion Dufresne (1995); MD106; MD972151; MD97-2151; South China Sea
    Type: Dataset
    Format: text/tab-separated-values, 3150 data points
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