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  • 1
    ISSN: 1432-0495
    Keywords: Coastal lagoon ; Metallic concentration ; Multivariate analysis ; Depositional environment ; Anthropogenic discharge
    Source: Springer Online Journal Archives 1860-2000
    Topics: Geosciences
    Notes: Abstract In the last decade, the Atlantic coast of south-eastern Brazil has been affected by increasing deforestation and anthropogenic effluents. Sediments in the coastal lagoons have recorded the process of such environmental change. Thirty-seven sediment samples from three cores in Piratininga Lagoon, Rio de Janeiro, were analyzed for their major components and minor element concentrations in order to examine geochemical characteristics and the depositional environment and to investigate the variation of heavy metals of environmental concern. Two multivariate analysis methods, principal component analysis and cluster analysis, were performed on the analytical data set to help visualize the sample clusters and the element associations. On the whole, the sediment samples from each core are similar and the sample clusters corresponding to the three cores are clearly separated, as a result of the different conditions of sedimentation. Some changes in the depositional environment are recognized using the results of multivariate analysis. The enrichment of Pb, Cu, and Zn in the upper parts of cores is in agreement with increasing anthropogenic influx (pollution).
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    Springer
    Geo-marine letters 4 (1984), S. 77-82 
    ISSN: 1432-1157
    Source: Springer Online Journal Archives 1860-2000
    Topics: Geosciences
    Notes: Abstract Core 7710, recovered on the George Bligh/Rockall Channel, is composed of fine grained ocher-colored sediments rich in ferriferous smectite (montmorillonite, beidellite). These sediments were deposited during early Eocene in a shallow marine environment. Their mineralogic, chemical and isotopic constituents indicate subaerial weathering of lower Eocene intermediate igneous rocks (ferrodiorite, marscoiite) eroded from the still-emergent George Bligh and Rockall Banks. Lack of any post Eocene Sediments may be due to major morphologic and hydrologic changes forming sedimentation gaps.
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  • 3
    Electronic Resource
    Electronic Resource
    Amsterdam : Elsevier
    Solid State Ionics 74 (1994), S. 29-35 
    ISSN: 0167-2738
    Keywords: Crystal structure ; Fluorides ; Ionic motions ; Mixed alkali zirconium fluorides ; NMR
    Source: Elsevier Journal Backfiles on ScienceDirect 1907 - 2002
    Topics: Physics
    Type of Medium: Electronic Resource
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  • 4
    ISSN: 1432-1157
    Source: Springer Online Journal Archives 1860-2000
    Topics: Geosciences
    Notes: Abstract Data obtained from mineralogical and geochemical analyses of piston and gravity cores, recovered from an area off Lisbon (Portugal) to the Alboran Sea (Mediterranean), serve as a basis for better understanding the past 18,000 years of hydrological exchanges at Gibraltar. Tracers used in this study are smectite, kaolinite, Ta, Th, La. One of the primary sources of particles both into and out of the Mediterranean is the Guadalquivir River. These particles are transported back into the Atlantic in the Mediterranean outflow water, and deposited along the Iberian slope. No evidence for reversal of this outflow current was found in those cores, since 18,000 years B.P.
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  • 5
    ISSN: 1573-5117
    Keywords: mega-tidal estuaries ; budget of substances ; trace metals
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology
    Notes: Abstract Evaluation of the quantity of estuarine flux material carried into the ocean, is difficult. High tides produce major oscillations in ocean waters and suspended matter (S.M.) near river mouths and, therefore, direct measurements at the river outlet do not represent real expulsions of S.M. The temperate climate, characterised by important seasonal variations throughout the year, induces significant hydrologic variations and consequently material fluxes into the ocean. Hence, it is difficult to represent measurements with respect to the time, season and especially the year, during which they take place. The Gironde estuary is a good example of this type of estuary, and shows that the evaluation of flux material can only be made from the following equation: expulsion = fluviatile inputs-deposits. Measurements are made from the fluxes of S.M. and from a few metals such as Zn, Cu, and Pb. It took three consecutive years (1976–1979) to carry out our measurements, which helped us to develop a general idea of the chief components of the system and to determine the flux variations. According to the results, important variations occur from year to year, particularly as far as S. M. is concerned. The estuary, thanks to its significant oscillating stock of S.M. (turbidity maximum), behaves as a regulator for the metals. In a surplus year it acts as a sink, and in a deficit year it acts as a source.
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  • 6
    ISSN: 1573-5117
    Keywords: mega-tidal estuaries ; budget of substances ; trace metals
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology
    Notes: Abstract Evaluation of the quantity of estuarine flux material carried into the ocean, is difficult. High tides produce major oscillations in ocean waters and suspended matter (S.M.) near river mouths and, therefore, direct measurements at the river outlet do not represent real expulsions of S.M. The temperate climate, characterised by important seasonal variations throughout the year, induces significant hydrologic variations and consequently material fluxes into the ocean. Hence, it is difficult to represent measurements with respect to the time, season and especially the year, during which they take place. The Gironde estuary is a good example of this type of estuary, and shows that the evaluation of flux material can only be made from the following equation: expulsion = fluviatile inputs-deposits. Measurements are made from the fluxes of S.M. and from a few metals such as Zn, Cu, and Pb. It took three consecutive years (1976–1979) to carry out our measurements, which helped us to develop a general idea of the chief components of the system and to determine the flux variations. According to the results, important variations occur from year to year, particularly as far as S. M. is concerned. The estuary, thanks to its significant oscillating stock of S.M. (turbidity maximum), behaves as a regulator for the metals. In a surplus year it acts as a sink, and in a deficit year it acts as a source.
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  • 7
    Publication Date: 2015-08-14
    Description: New insights into the formation of interstellar formamide, a species of great relevance in prebiotic chemistry, are provided by electronic structure and kinetic calculations for the reaction NH 2 + H 2 CO -〉 NH 2 CHO + H. Contrarily to what previously suggested, this reaction is essentially barrierless and can, therefore, occur under the low temperature conditions of intestellar objects thus providing a facile formation route of formamide. The rate coefficient parameters for the reaction channel leading to NH 2 CHO + H have been calculated to be A = 2.6 x 10 –12  cm 3  s –1 , β = –2.1 and = 26.9 K in the range of temperatures 10–300 K. Including these new kinetic data in a refined astrochemical model, we show that the proposed mechanism can well reproduce the abundances of formamide observed in two very different interstellar objects: the cold envelope of the Sun-like protostar IRAS16293–2422 and the molecular shock L1157-B2. Therefore, the major conclusion of this Letter is that there is no need to invoke grain-surface chemistry to explain the presence of formamide provided that its precursors, NH 2 and H 2 CO, are available in the gas phase.
    Print ISSN: 1745-3925
    Electronic ISSN: 1745-3933
    Topics: Physics
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  • 8
    Publication Date: 2017-07-28
    Description: The purpose of this work is to investigate the crystal growth parameters necessary or sufficient to obtain a crystal specifically of gem quality. We assume adequate chemistry is available. First, nucleation must occur with only a limited number of nuclei, otherwise too many crystals will be produced, and they will be too small to be faceted into a gem. Two growth mechanisms are readily documented for gems: Most commonly there is slow growth, driven by a spiral growth mechanism, leading to large single individuals. There are only a few examples of fast growth leading to gem-quality edifices: examples include "gota de aceite" Colombian emerald or the dendritic "pseudo cube" for gem diamonds. We have not documented the intermediate conditions between these two extremes in the Sunagawa diagram, which would correspond to 2D nucleation growth. The presence of inclusions is to be limited to desirable ones. Thus, in general, a good stability of the growth interface is the best guarantee of good clarity in the final gem. As for the interface, in general, growth conditions must be relatively stable over the period necessary to achieve growth. Perhaps surprisingly, it has become well documented that gem-quality near-colorless diamonds may have experienced quite a complex growth history. Therefore, the term stability has to be re-defined for each system producing a given gem. The length of time it takes to achieve crystallization of the gem has rarely been studied or estimated. Scientific evidence from experimental petrology and the growth of synthetic gems indicates that it does not take millions of years to grow a gem, but that this exercise may be achieved in a week to, arguably, a few years at the most. Available free space to grow does not appear always necessary, but it helps. Otherwise deformation, inclusions, and other negative effects may occur. Finally, no dramatic post-growth events, such as fracturing or etching, should affect the gem crystal.
    Print ISSN: 0008-4476
    Topics: Geosciences
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  • 9
    Publication Date: 1994-12-01
    Print ISSN: 0167-2738
    Electronic ISSN: 1872-7689
    Topics: Physics
    Published by Elsevier
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  • 10
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