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  • AERODYNAMICS  (153)
  • Chemical Engineering  (129)
  • 1
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 29 (1983), S. 854-858 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Following secondary recovery processes in conventional light oil reservoirs, more than half the original oil in place may remain trapped as a discontinuous phase. During the previous recovery processes these oil ganglia have been pinched off by capillary forces and remain immobile while the continuous phase which surrounds them is able to flow freely. Furthermore if a portion of this oil is mobilized in a tertiary recovery process the conditions required to apply Darcy's equation to the flow of either phase are violated. These are also problems which are encountered during in-situ recovery techniques in tar sands where the mobilization of the heavy oil occurs as a discontinuous phase. In this paper the relevant flow equations are derived. Also a parameter is deduced which directly determines the criterion for mobilization.
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  • 2
    Electronic Resource
    Electronic Resource
    Brookfield, Conn. : Wiley-Blackwell
    Polymer Composites 14 (1993), S. 503-514 
    ISSN: 0272-8397
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Design of molding tools and molding cycles for sheet molding compounds (SMC) is often expensive and time consuming. Computer simulation of the compression molding process is a desirable approach for reducing actual experimental runs. The focus of this work is to develop a computer model that can simulate the most important features of SMC compression molding, including material flow, heat transfer, and curing. A control volume/finite element approach was used to obtain the pressure and velocity fields and to compute the flow progression during compression mold filling. The energy equation and a kinetic model were solved simultaneously for the temperature and conversion profiles differential scanning calorimetry (DSC) was used to experimentally measure the polymer zation kinetics. A rheometrics dynamic analyzer (RDA) was used to measure the rheological changes of the compound. A series of molding experiments was conducted to record the flow front location and material temperature. The results were compared to simulated flow front and temperature profiles.
    Additional Material: 7 Ill.
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  • 3
    Electronic Resource
    Electronic Resource
    Stamford, Conn. [u.a.] : Wiley-Blackwell
    Polymer Engineering and Science 32 (1992), S. 1366-1371 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: For relatively soft polymer coatings on soda-lime glass substrates the indentation load increases substantially when the indenter penetrates into the glass substrate since the glass can now directly support some of the indenter load. A model for the indentation load-depth behavior is developed by accounting for the indentation load shared by the coating and substrate. This model accounts for the additional load supported by the coating due to the pile-up of coating material underneath the indenter. The model predicts the indentation behavior as a function of coating and substrate hardnesses and coating thickness. Comparison of the model to experimental data for a wide range of polymer coatings (two epoxies, epoxy acrylate, and urethane acrylate) on soda-lime glass substrates shows good agreement.
    Additional Material: 8 Ill.
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  • 4
    Electronic Resource
    Electronic Resource
    Stamford, Conn. [u.a.] : Wiley-Blackwell
    Polymer Engineering and Science 32 (1992), S. 1372-1378 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Polymer coatings are widely used to protect glass from indentation damage. A model for the strength degradation that occurs when a sharp indenter penetrates through the coating is developed by accounting for the indentation load shared by the coating and substrate. This model accounts for the additional load supported by the coating due to the pile-up of coating material underneath the indenter. The model predicts the strength degradation as a function of indentation load, coating and substrate hardnesses, and coating thickness. Comparison of the model to experimental data for a wide range of polymer coatings (two epoxies, epoxy acrylate, and urethane acrylate) on soda-lime glass substrates shows good agreement.
    Additional Material: 10 Ill.
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  • 5
    Electronic Resource
    Electronic Resource
    Stamford, Conn. [u.a.] : Wiley-Blackwell
    Polymer Engineering and Science 30 (1990), S. 1500-1503 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: A new capillary gas chromatography method to monitor a residual monomer in a polymer is described. A short (5 m) crosslinked methyl silicone fused silica capillary column with flame ionization detection gave good separation efficiency and parts-per-million detection limits. Capillary gas-liquid chromatography was superior to packed column analysis (SP 1000) in terms of both analytical utility and ease of use. This technique may prove useful for monitoring other monomer/polymer systems.
    Additional Material: 3 Ill.
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  • 6
    Electronic Resource
    Electronic Resource
    Stamford, Conn. [u.a.] : Wiley-Blackwell
    Polymer Engineering and Science 4 (1964), S. 102-106 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: The basic requirements for optimization of filament-wound pressure vessels are a high strength-to-density ratio of the fiberglass-resin composite and an arrangement of the glass fibers in such fashion that each fiber carries, at a given pressure, the same constant load throughout the cylindrical portion as well as the end closures. The basic relations governing the isotensoidal design are derived, and the ideal shape of the end closure is defined. The relative merits of geodesic and “in-plane” wrapping are discussed. Structrual efficiencies accomplished in several practical applications are reviewed.
    Additional Material: 3 Ill.
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  • 7
    Electronic Resource
    Electronic Resource
    Stamford, Conn. [u.a.] : Wiley-Blackwell
    Polymer Engineering and Science 27 (1987), S. 764-771 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: A number of studies on the kinetics of physicochemical processes are described. The methods used are shown to be potentially useful for making time-temperature predictions and for optimizing process variables. Examples described include (1) the long-term prediction of the performance of a plasticized polyvinyl chloride and doped polyacetylenes; (2) the polymerization of a monomer and the optimization of time, temperature, and initiator concentration variables; (3) analysis of an order/disorder transition in a thermochromic polymer; (4) the crystallization of polymers and the effect of a nucleating agent; and (5) the crystallization of an amorphous metallic glass. The theoretical background, significance, scope, and limitations of these measurements are also discussed.
    Additional Material: 16 Ill.
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  • 8
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 35 (1989), S. 1346-1350 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Andritsos and Hanratty (1978b) have shown that the increase in interfacial drag caused by waves in stratified gas-liquid flows is related to the wave steepness. Recent analyses of finite amplitude Kelvin-Helmholtz waves are used to develop a correlation for the ratio of the wave height to wavelength.
    Additional Material: 5 Ill.
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  • 9
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 35 (1989), S. 1962-1974 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: A computer simulation of turbulent flow in a channel is used to detect flow patterns related to the production of Reynolds stress. It is found that quadrant 2 and quadrant 4 events possess a streaky structure in the viscous wall region and that these events can be best understood by examining the velocity field in the y-z plane. Large turbulence production in the viscous wall region is found to occur in updrafts and downdrafts associated with closed eddies. These eddies, on average, have a spanwise dimension of 50 wall units and a streamwise dimension of 400-450 wall units. They are often seen to originate from small attached eddies at the wall.
    Additional Material: 18 Ill.
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  • 10
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 41 (1995), S. 2198-2211 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: In roll coating as in other coating processes the coating liquid often suffers changes in properties on the time of the coating flow, that is, from fractions of a second upward depending on the amount of recirculation and recycling. The agents of change may be chemical reaction, colloidal aggregation, or evaporation. Hence the mean residence time and the residence time distribution of the liquid are important to designers and operators of coating processes. Here, building on the examination of roll-coating systems by Benjamin et al. (1995), the residence times of liquid coated by representative arrays of multiple rolls in the “forward roll” mode and relatively starved feed condition (neglecting the possibly significant effects of “rolling banks” and other internal recirculations when they are present) are analyzed. The dynamic response of these transfer coaters to step changes in the feed gap and to periodic gap changes, as from roll and bearing run-out, are also analyzed. No reports of operating or laboratory experiments are available for comparison. Nevertheless the results make plain how these quality-limiting features may depend don the number of rolls used; their sizes, speed, and arrangement, and the properties of the coating liquid.
    Additional Material: 18 Ill.
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