ISSN:
0021-8995
Keywords:
Chemistry
;
Polymer and Materials Science
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
,
Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
,
Physics
Notes:
This article describes the hydrolytic degradation of a series of nylons based on methylated L-tartaric acid and diamines. These polytartaramides were prepared by a solution polycondensation process using bis(pentachlorophenyl)-2,3-O-dimethyl-L-tartrate and N,N′-bis(trimethylsilyl)alkanediamines with 6, 8, or 12 methylene groups. The stereoregular optically active polyamides obtained were soluble in chloroform and showed intrinsic viscosities between 1.0 and 2.7 dL g-1. The degradation of these polytartaramides in the form of discs has been investigated in buffered salt solutions of pH 2.3, 7.4, and 10.6, and at temperatures of 37, 55, and 70°C. The degradation was monitored by following the changes in molecular weight, mass loss, chemical constitution, and thermal properties. Our results show that these polytartaramides degrade slowly at 37°C, with a degradation rate highly depending upon the number of methylenes in the diamine unit of the polyamide. The pH of the medium has also a great influence on degradation, as well as the temperature, with an important hydrolysis rate enhancement at 70°C. © 1995 John Wiley & Sons, Inc.
Additional Material:
10 Ill.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/app.1995.070580105
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