ISSN:
0044-2313
Keywords:
Chemistry
;
Inorganic Chemistry
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Description / Table of Contents:
1,2-Bis-(triphenylphosphorane-ylidene-amino)ethane as a Bidentate Ligand in Transition Metal ComplexesThe reactions of Ph3P=N—C2H4—N=PPh3 with transition metal halogenides MX2 give according to eq. (1) novel bisiminophosphorane complexes of the type M(Ph3PNC2H4 NPPh3)X2 (M = Co, X = Cl 1 a, Br 1 b, J 1 c; M = Ni, X = Cl 2 a, Br 2 b, J 2 c, M = Hg, X = Cl 3, M = Cd, X = Cl 4). The preparation, properties, magnetic moments, and structure of the new complexes are reported
Notes:
Die Umsetzungen von Ph3P=N—C2H4—N=PPh3 mit Übergangsmetallhalogeniden MX2 führen gemäß Gl. (1) zu neuartigen Bisiminophosphoran-Komplexen des Typs M(Ph3PNC2H4NPPh3)X2 (M = Co, X = Cl 1 a, Br 1 b, J 1 c, M = Ni, X = Cl 2 a, Br 2 b, J 2 c; M = Hg, X = Cl 3, M = Cd, X = Cl 4). Es wird über Darstellung, Eigenschaften, magnetische Momente sowie Struktur der neuen Komplexe berichtet.
Additional Material:
2 Tab.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/zaac.19754130106
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