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  • 1
    ISSN: 1434-1948
    Keywords: 2-Acetylpyridine 4-methylthiosemicarbazone ; Palladium ; Platinum ; Group-12 metal(II) complexes ; Chemistry ; General Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Reaction of 2-acetylpyridine 4-methylthiosemicarbazone (H4ML) with halides of zinc(II), cadmium(II), and mercury(II) afforded complexes of the form [M(H4ML)X2] [M = ZnII (1-3), CdII (4-6) or HgII (7-9); × = Cl, Br, or I]. Reaction of H4ML with K2PdCl4 and K2PtCl4 gave compounds of the form [M(4ML)Cl] [M = PdII (10) or PtII (11)]. In all the new compounds, which were characterized by elemental analyses, conductance measurements, and electronic, IR and 1H- and 13C-NMR spectroscopy, and by 113Cd-, 195Pt-, or 199Hg-NMR spectroscopy when relevant, the ligand is N,N,S-tridentate, coordinating to the metal centre through its pyridine and azomethine nitrogen atoms and its thiocarbonyl sulfur atom, as was confirmed by X-ray diffraction studies in the cases of 4· 2 DMSO, 5· 2 DMSO, 6· 2 DMSO, 7· 2 DMSO, 10, and 11. In in-vitro assays, only [Zn(H4ML)Cl2] and [Zn(H4ML)Br2] showed some sign of antifungal activity against Aspergillus niger or Paecilomyces variotii.Supporting information for this article is available on the WWW under http://www.wiley-vch.de/contents/jc_2005/1999/98381_s.pdf or from the author.
    Additional Material: 8 Ill.
    Type of Medium: Electronic Resource
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  • 2
    Publication Date: 2012-05-26
    Description: This paper deals with the generation of accurate, dense and coloured 3D models of outdoor scenarios from scanners. This is a challenging research field in which several problems still remain unsolved. In particular, the process of 3D model creation in outdoor scenes may be inefficient if the scene is digitalized under unsuitable technical (specific scanner on-board camera) and environmental (rain, dampness, changing illumination) conditions. We address our research towards the integration of images and range data to produce photorealistic models. Our proposal is based on decoupling the colour integration and geometry reconstruction stages, making them independent and controlled processes. This issue is approached from two different viewpoints. On the one hand, given a complete model (geometry plus texture), we propose a method to modify the original texture provided by the scanner on-board camera with the colour information extracted from external images taken at given moments and under specific environmental conditions. On the other hand, we propose an algorithm to directly assign external images onto the complete geometric model, thus avoiding tedious on-line calibration processes. We present the work conducted on two large Roman archaeological sites dating from the first century A.D., namely, the Theatre of Segobriga and the Fori Porticus of Emerita Augusta, both in Spain. The results obtained demonstrate that our approach could be useful in the digitalization and 3D modelling fields.
    Electronic ISSN: 1424-8220
    Topics: Chemistry and Pharmacology , Electrical Engineering, Measurement and Control Technology
    Published by MDPI Publishing
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