ISSN:
0899-0042
Schlagwort(e):
1,3-oxathiolane
;
chiral α-methylbenzylamine
;
optical resolution
;
Chemistry
;
Organic Chemistry
Quelle:
Wiley InterScience Backfile Collection 1832-2000
Thema:
Chemie und Pharmazie
Notizen:
cis- and trans-5-Ethoxy-1,3-oxathiolane-2-carboxylic acids were obtained in pure form. The cis isomer was resolved into its enantiomers through diastereoisomeric salt formation with enantiomerically pure α-methylbenzylamine. Reduction of the salt followed by benzoylation led to 2-benzoyloxymethyl-5-ethoxy-2(R)-5(S)-1,3-oxathiolane and 2-benzoyloxymethyl-5-ethoxy-2(S)-5(R)-1,3-oxathiolane, useful intermediates in nucleoside chemistry. © 1993 Wiley-Liss, Inc.
Zusätzliches Material:
2 Ill.
Materialart:
Digitale Medien
URL:
http://dx.doi.org/10.1002/chir.530050210
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