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  • 1
    Electronic Resource
    Electronic Resource
    Formation of free radicals in the low-temperature fluorination of polymers (1996)
    Springer
    Russian chemical bulletin 45 (1996), S. 1623-1627 
    Details
    ISSN: 1573-9171
    Keywords: polymers ; fluorination ; free radicals
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Notes: Abstract The formation of free radicals in the process of direct fluorination of natural and synthetic polymers at temperatures close to 77 K was studied by ESR. The maximum concentrations of radicals, (1017–5·1018 spin g−1) and their complete oxidation were observed in the temperature interval from 77 to 250 K at a fluorine pressure of 30 Torr. The initiation of chain halogenation, which consists of homolytic breaking of chemical bonds to yield free-radical intermediates. was examined in the framework of the multi-center synchronous transitions model.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1007/BF01431798
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