ALBERT

Notizen: In pure oxygen at moderate temperatures of 200 °C, an fcc C60 transforms into amorphous carbon-oxygen compounds and the icosahedral C60 molecular structure is destroyed. The maximum oxygen uptake of pure C60, O/C60, is 12. Isothermal TGA transformation curves are sigmoid-shaped with the kinetic exponent n∼5/2 which conforms with a two-dimensional nucleation and growth mode. The heat of formation for the carbon-oxygen compounds is 90 kcal/mol O, and the formation energy for the reaction: 60C (graphite)→C60 molecule is estimated to be ∼600 kcal/mol.

Notizen: Summary Hydrostatic and nonhydrostatic simulation models are employed to study the intensification of a terrain drag-induced dryline. The study develops a multi-stage theory for the evolution of the dryline including the concentration of potential vorticity accompanying meso-gamma scale dryline “bulges”. The numerical simulations indicate three fundamental stages of dryline intensification all of which are either directly or indirectly a result of the terrain-drag on the mid/upper-tropospheric jet stream by the Front Range of the Colorado Rocky Mountains. The first stage involves the downward momentum flux accompanying a large amplitude hydrostatic mountain wave which induces a downslope windstorm along the lee slopes. The surge of momentum (i.e., the dry, warm air associated with the downslope windstorm) propagates down the leeslope and modifies an existing weak dryline boundary. As the downslope windstorm initiates an undular bore along the lee slopes, the high momentum gradient which propagates downstream accompanying the bore, as well as the strong lower tropospheric sinking motions ahead of the bore, contract the scale of the surface moisture boundary between the dry air from above the leeslope and the moist air over the High Plains. This process further strengthens the dryline. The second stage involves the coupling of the terrain drag-induced along-stream ageostrophic front within the midtroposphere to the boundary layer through a thermally-indirect circulation. As the along-stream ageostrophic circulation intensifies within the middle troposphere down-stream from the mountain wave, sinking air parcels originating above 40 kPa descend to below 60 kPa over the High Plains where surface pressures are, only ∼85 kPa. These descending air parcels within the upstream branch of the along-stream ageostrophic thermally-indirect circulation contain high values of momentum and very low dewpoint values. As the planetary boundary layer (PBL) deepens due to surface warming during the morning hours, momentum and dry air from the midtropospheric along-stream ageostrophic front are entrained into the PBL. This process amplifies the bore-induced hydrostatic dryline bulge via low-level ageostrophic confluence. Finally, regions of low Richardson number (arising from strong vertical shears) within the amplifying midtropospheric along-stream ageostrophic thermally-indirect circulation become preferred regions for the development of non-hydrostatic evanescent internal gravity waves. These waves are embedded within the hydrostatic along-stream front above the low-level dryline and are accomapanied by very significant values of vertical momentum flux which act to focus the meso-gamma scale structure of the dryline into smaller scale bulges where low-level winds and vorticities are very high. This meso-gamma scale process follows the hydrostatic tilting and vortex tube stretching which creates meso-beta scale maxima of mid-lower tropospheric vorticity. The turbulent momentum fluxes accompanying wavebreaking within the nonhydrostatic dryline bulge create very large (i.e., stratospheric values of) potential vorticity near 70 kPa due to the nonconservation of potential vorticity on isentropic surfaces.

Notizen: Summary The problem of along-stream ageostrophic frontogenesis is studied by employing a numerical model at meso-alpha and meso-beta scales in simulations of the downstream circulations over the Front Range of the Rocky Mountains. Three-dimensional real data simulations at these two scales of motion are used to diagnose the transition from semigeostrophic cross-stream frontogenesis accompanying a propagating baroclinic upper-level jet streak to midtropospheric along-stream ageostrophic frontogenesis. This along-stream ageostrophic frontogenesis results from the perturbation of the jet streak by the Rocky Mountain range. The case study represents an example of internal wave dynamics which are forced by the drag of the Rocky Mountains on a strong jet streak in the presence of a low-level inversion. The simulation results indicate that, unlike semi-geostrophic frontogenesis, a front (which is alligned perpendicular to the axis of the jet stream) may form when significant adiabatic heating occurs within a stratified shear flow over horizontal length scales shorter than the Rossby radius of deformation. The mechanism responsible for the frontogenesis is the growth of the divergent along-stream wind velocity component which becomes coupled to the front's along-stream pressure gradient force. This nonlinear interaction produces hydrostatic mesoscale frontogenesis as follows: 1) vertical wind shear in the along-stream plane strengthens resulting in the increasingly nonuniform vertical variation of horizontal temperature advection as the ageostrophic wind component grows in magnitude downstream of the meso-scale terrain-induced adiabatic heating, 2) increasing along-stream differential vertical motions (i.e., along-stream thermally indirect circulation with warm air sinking to the west and cold air rising to the east) tilt the vertical gradient of isentropes into the horizontal as the vertical temperature gradient increases due to the previous process in proximity to horizontal gradients in the along-stream component of the ageostrophic wind, 3) as tilting motions act to increase the along-stream horizontal temperature gradient, the along-stream confluence acts to nonuniformly increase the along-stream frontal temperature gradient which increases the along-stream pressure gradient force resulting in further accelerations, ageostrophy, and frontal steepening as part of a scale contraction process. The evolution of the aforementioned processes results in the three-dimensional hydrostatic frontogenesis accompanying the overturning of isentropic surfaces. These adjustments act to turn air parcels to the right of the southwesterly geostrophic wind vector at successively lower atmospheric levels as the scale contraction continues. This simulated along-stream front is verified from diagnostic analysis of the profiler-derived temperature and wind fields.

Notizen: Abstract An effective numerical procedure, based on the Galerkin method, for finding solutions of the stationary traveling wave type in the complete formulation is proposed for the case of viscous liquid films. Examples of a viscous film flowing freely down a vertical surface have been calculated. The calculations have been made for various values of the dimensionless surface tension γ, including γ=0. The method makes it possible to predict a number of bifurcations that occur as γ decreases. The existence of numerous families of stationary traveling waves when γ ≫ 1 was demonstrated in [6]. The present study shows that as γ→1 all but one of these families of wave solutions disappear. The shape of the periodic and solitary waves and the pressure distribution in the film are found for various γ. When γ=0 and the wave number α is fairly small, the periodic solution has a singularity, as predicted in [14]: at the crest of the wave a corner point appears; the angle between the tangents at this point ϕ=140–150. The method proposed can be used to calculate other wavy film flows.

Notizen: Imidazoles have for some time been recognized as curing agents for epoxy resins. Once the resin and the imidazole compound are mixed there is a relatively short time in which the mixture can be used, since the polymerization (curing) reaction occurs to some extent even at room temperature causing the reaction mixture to thicken. In order to circumvent this problem we have found that imidazoles can be complexed with organo-lanthanide compounds thereby tying up the imidazole and retarding its rate of reaction in the cure of epoxy materials at ambient temperatures. When it is desired to enhance the rate of cure the temperature of the mixture is simply raised. This paper concerns studies of the epoxy cure reaction with the M(THD)3-IM series. M represents the lanthanide metals Eu, Ho, Pr, Dy, Yb, and Gd, and THD is 2,2,6,6-tetramethyl-3,5-heptanedione. Cure reactions were followed by differential scanning calorimetry and in some cases by infrared spectroscopy. We have demonstrated that these organo-lanthanide-imidazole complexes are effective thermally latent curing agents for epoxy resins. At a temperature of 150°C cure is quite rapid. In the course of these studies it has also been determined that there is an inverse correlation between the lanthanide ionic radius in the complex and the temperature at which the cure reaction occurs. Thus the Yb compound, where the imidazole is most strongly bound, cures at the highest temperature and Pr, where imidazole is bound most weakly, at the lowest. Consistent with these facts is the observation that the Yb compound also gives the longest latency period when mixed with epoxy resin.

Notizen: We have prepared comblike polymers based on styrene-maleic anhydride and ethylene-maleic anhydride copolymer backbones. Reactions have been carried out in which the cyclic anhydrides were ring opened with the concomitant formation of ester groups on one of the carbonyl functions. The remaining carbonyl group is part of a carboxylic acid. The alcohol moieties are either the monomethyl ethers of triethylene glycol or of polyethylene glycol (MW 350). The resulting polymers were then converted to their lithium salts.Complex impedance plane measurements of the ionic conductivity in these lithiated polymers have been performed. Cole-Cole plots indicate that there is no electronic contribution to the overall conductivity. The ionic conductivity in the case of the triethylene glycol comb polymer is about 10-9 S cm-1, whereas that of the polymer with the longer ethylene oxide chain is 10-7 S cm-1 at room temperature. From the chemical nature of these polymers, it is presumed that all the conductivity is due to the mobility of the Li ion. These data will be compared to the results other laboratories have had with different single-ion conducting polymers.