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  • 1995-1999  (417)
  • 1990-1994  (360)
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  • 1
    Unbekannt
    Basel, Boston, Berlin : Birkhäuser
    Beschreibung / Inhaltsverzeichnis: The 1993 Southwest Hokkaido Earthquake of Magnitude 7. 9 (July 12, 22: 17 JST) caused serious tsunami disasters in the southwestern part of Hokkaido, particularly on Okushiri Island (a tiny island off the southwest coast of Hokkaido with a population of about 4,500 at the time of earthquake). Of 230 casualties, including 28 missing, about 200 deaths are attributable to the tsunami. We have conducted detailed field surveys of tsunami disasters to learn lessons from this costly natural experiment for the future prevention of similar tsunami disasters. Our field work was conducted in four surveys totaling 39 days. During the first field survey (July 16 through July 21, 1994), we worked mostly on the estimation of the subsidence of Okushiri Island during the earthquake. Hence, our main work on tsunami disasters initiated from the second field survey (July 31 through Aug. 15, 1994). Several groups have conducted detailed surveys of the distribution of tsunami runup height as measured from the level of sea water (TsUJI et al. , 1 994a, b; MATSUTOMI and SHUTO, 1994; GOTO et al. , 1994). Such a precise runup height distribution is essential for characterizing tsunami, including its overall size. Indeed, the height distribution is the fundamental data for inferring earthquake source parameters through the simulation of tsunami generation (TAKAHASHI et al. , 1994; IMAMURA et al. , 1994; TSUJI et al. , 1994a; SATAKE and TANIOKA 1994; ABE, 1994; TANIOKA et al. , in review).
    Seiten: Online-Ressource (VII, 517 Seiten)
    ISBN: 9783034872799
    Sprache: Englisch
    Standort Signatur Erwartet Verfügbarkeit
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  • 2
    Digitale Medien
    Digitale Medien
    College Park, Md. : American Institute of Physics (AIP)
    The Journal of Chemical Physics 111 (1999), S. 6356-6362 
    ISSN: 1089-7690
    Quelle: AIP Digital Archive
    Thema: Physik , Chemie und Pharmazie
    Notizen: The laser-induced fluorescence spectrum of the B˜ 2A″→X˜ 2A″ transition of the CD2CFO radical has been observed in the region 316–335 nm. The radical was produced by 193 nm photolysis or by fluorine atom reaction with acetyl-d3 fluoride. The spectrum of CD2CFO was similar to that of CH2CFO reported previously except for small isotope shifts in the range 7–343 cm−1. The isotope shifts support the assignment of these spectra to fluorinated vinoxy radicals, and rule out the alternate assignment to FCO proposed by others. The X˜→B˜ electronic transition energy (T0) for CD2CFO was measured to be 29 867 cm−1, which is only 7 cm−1 lower than that for CH2CFO. From an analysis of the laser-induced single vibronic level fluorescence, some of the vibrational frequencies can be assigned for the ground electronic state; ν3(CO str.)=1735; ν4(CD2 sciss.)=1043; ν5(CF str.)=1248; ν6(CD2 rock.)=774; ν7(CC str.)=863; ν8(CCF bend)=597; and ν9(CCO bend)=370 cm−1. For the B˜ 2A″ state, ν3=1772; ν4=1073; ν5=1241; ν6=783; ν7=827; ν8=530; and ν9=370 cm−1. These assignments are supported by ab initio calculations. Among these fundamental frequencies, the ν4 and ν6 modes showed the largest isotope shifts, although isotope effects were observed in all the above vibrational fundamentals. The radiative lifetimes of the excited CD2CFO and the quantum yield of formation of the CH2CFO radical from photolysis of CH3CFO at 193 nm are also reported. © 1999 American Institute of Physics.
    Materialart: Digitale Medien
    Standort Signatur Erwartet Verfügbarkeit
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  • 3
    Digitale Medien
    Digitale Medien
    College Park, Md. : American Institute of Physics (AIP)
    The Journal of Chemical Physics 107 (1997), S. 6998-7000 
    ISSN: 1089-7690
    Quelle: AIP Digital Archive
    Thema: Physik , Chemie und Pharmazie
    Notizen: Three new laser-induced fluorescence spectra have been observed when reacting oxygen atoms with halogenated ethylenes such as CHFCF2, CF2CHCl, CH2CCl2, CH2CHCl, and CHClCHCl. These new spectra are similar to those reported previously for the vinoxy (CH2CHO) and CH2CFO radicals, which suggests that they can be assigned to other halogenated vinoxy-type radicals. Recently Williams and Fleming assigned one of these LIF spectra to the FCO radical; additional experiments have been done to address this conflicting assignment. © 1997 American Institute of Physics.
    Materialart: Digitale Medien
    Standort Signatur Erwartet Verfügbarkeit
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  • 4
    ISSN: 1520-4804
    Quelle: ACS Legacy Archives
    Thema: Chemie und Pharmazie
    Materialart: Digitale Medien
    Standort Signatur Erwartet Verfügbarkeit
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  • 5
    ISSN: 1520-4804
    Quelle: ACS Legacy Archives
    Thema: Chemie und Pharmazie
    Materialart: Digitale Medien
    Standort Signatur Erwartet Verfügbarkeit
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  • 6
    Digitale Medien
    Digitale Medien
    [S.l.] : American Institute of Physics (AIP)
    Journal of Applied Physics 75 (1994), S. 2061-2068 
    ISSN: 1089-7550
    Quelle: AIP Digital Archive
    Thema: Physik
    Notizen: Structure dependence of electrical properties was investigated for amorphous and epitaxial thin films of chloroaluminumphthalocyanine vacuum deposited on both glass and KCl. The extrinsic conductivity in the dark was improved by elevating substrate temperatures, depending on the morphological change from granular, discontinuous films deposited at a substrate temperature of 25 °C to uniform, continuous ones at 250 °C. The photocurrents under monochromatic light illumination increased in proportion to the amount of adsorbed O2 in the amorphous films on glass. A regular doping form of O2 in the epitaxial film on KCl could enhance photocarrier generation. The granular, discontinuous morphology in the films caused a frequent charge-carrier recombination at the grain boundaries and defect sites. In the intrinsic region the amorphous films exhibited a higher dark conductivity due to the π-electron interaction between the randomly arranged molecules and gave a moderate activation energy for conduction. The epitaxial film with a regular orientation exhibited a significantly higher activation energy for intrinsic dark conduction because of a weak molecular interaction between the standing molecular columns.
    Materialart: Digitale Medien
    Standort Signatur Erwartet Verfügbarkeit
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  • 7
    Digitale Medien
    Digitale Medien
    College Park, Md. : American Institute of Physics (AIP)
    The Journal of Chemical Physics 107 (1997), S. 3569-3575 
    ISSN: 1089-7690
    Quelle: AIP Digital Archive
    Thema: Physik , Chemie und Pharmazie
    Notizen: In the present article, the excitation energies of the all-trans and the 11,12s-dicis retinals were calculated by using the elongation method. The geometries of these molecules were optimized with the 4-31G basis set by using the GAUSSIAN 92 program. The wave functions for the calculation of the excitation energies were obtained with CNDO/S approximation by the elongation method, which enables us to analyze electronic structures of aperiodic polymers in terms of the exciton-type local excitation and the charge transfer-type excitation. The excitation energies were calculated by using the single excitation configuration interaction (SECI) on the basis of localized molecular orbitals (LMOs). The LMOs were obtained in the process of the elongation method. The configuration interaction (CI) matrices were diagonalized by Davidson's method. The calculated results were in good agreement with the experimental data for absorption spectra. In order to consider the isomerization path from 11,12s-dicis to all-trans retinals, the barriers to the rotations about C11–C12 double and C12–C13 single bonds were evaluated. © 1997 American Institute of Physics.
    Materialart: Digitale Medien
    Standort Signatur Erwartet Verfügbarkeit
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  • 8
    ISSN: 1089-7690
    Quelle: AIP Digital Archive
    Thema: Physik , Chemie und Pharmazie
    Notizen: Electronic and geometrical structures of bis(ethylenedithio)tetrathiafulvalene (BEDT-TTF) molecules are studied using ab initio molecular orbital methods. The optimized structure of a BEDT-TTF monomer is close to the experimental one within errors of 0.02 Å and 0.5 deg in bond length and angle, respectively, except the ethylene group. Ab initio parameters such as transfer integrals and Coulomb interactions are determined from the BEDT-TTF dimer and tetramer calculations. Using model Hamiltonians with the ab initio parameters, we investigate the electronic states based on the exact diagonalization method. The results show that the ground state has antiferromagnetic correlation which is consistent with experimental results. We study the effects of long-range Coulomb interactions employing the 2-D extended Hubbard model with the Hartree–Fock approximation. It is found that the ground state shows various phases; antiferromagnetic, charge ordering, and paramagnetic ones, controlled by the long-range interactions. © 1999 American Institute of Physics.
    Materialart: Digitale Medien
    Standort Signatur Erwartet Verfügbarkeit
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  • 9
    Digitale Medien
    Digitale Medien
    College Park, Md. : American Institute of Physics (AIP)
    The Journal of Chemical Physics 108 (1998), S. 10303-10308 
    ISSN: 1089-7690
    Quelle: AIP Digital Archive
    Thema: Physik , Chemie und Pharmazie
    Notizen: Photoinduced phase transition models between two distinct structures (acetylene and butatriene types) of polydiacetylene were investigated by using an elongation method. The geometries of these oligomers were optimized with ab initio self-consistent field. The wave functions for the calculation of the excitation energies were obtained with complete neglect of differential overlap in spectroscopy (CNDO/S approximation) by the elongation method. The excitation energies were calculated by using the single excitation configuration interaction method on the basis of localized molecular orbitals. The energy diagram for the phase transition is plotted and the structural change associated with the photoinduced excitation is discussed. © 1998 American Institute of Physics.
    Materialart: Digitale Medien
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  • 10
    Digitale Medien
    Digitale Medien
    College Park, Md. : American Institute of Physics (AIP)
    The Journal of Chemical Physics 103 (1995), S. 663-675 
    ISSN: 1089-7690
    Quelle: AIP Digital Archive
    Thema: Physik , Chemie und Pharmazie
    Notizen: We have recently proposed the elongation method which is a novel molecular orbital method at the Hartree–Fock level to calculate the electronic structures of large periodic or aperiodic polymers efficiently. This method has the idea of the successive connection of any fragments to obtain the electronic properties of large molecules with any units. In this approach, the stationary conditions of the electronic states against the size extension have been formulated. Studies for molecular systems have suggested that the elongation technique with the stationary conditions may be applicable to periodic systems described by the crystal orbital. A one-dimensional polymer, a two-dimensional surface, and a three-dimensional crystal with a local disordering part can be treated systematically by introducing the elongation technique into a large extended supercell model. In the present study, we develop a new quantum chemical approach for the study of locally perturbed periodic systems by the ab initio crystal orbital calculation. The description for the methodology of this approach is given in detail. Results of test applications to a perturbed two-dimensional surface are shown. A local adsorption of carbon monoxide on (001) surface composed with magnesium oxide is examined as a sample model to confirm the accuracy of ab initio crystal elongation method. The utility of our method is clarified by an application to the perturbed surface. © 1995 American Institute of Physics.
    Materialart: Digitale Medien
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