ISSN:
1572-8854
Keywords:
Thiolato complex
;
dinuclear platinum complex
;
biomolecular model
Source:
Springer Online Journal Archives 1860-2000
Topics:
Geosciences
,
Physics
Notes:
Abstract The title compound, aefh-tetrachloro-cg,db-bis{μ-[(1-methyl-3-piperidinyl)methanethiolato]-μ-S,N}-diplatinum(II, IV) crystallizes in the monoclinic system, space group P 21/a , with the following crystal data: a = 13.502(2) Å, b = 12.323(2) Å, c = 13.720(3) Å and β = 105.92(2)°. It is a dinuclear Pt(II)–Pt(IV) mixed-valence thiolato complex and represents the first chelate compound of 3-mercaptomethyl-1-methyl piperidine. Each ligand is terdentate and simultaneously S,N-chelating and μ-bridging. The metal environment is approximately square-planar and octahedral for Pt(II) and Pt(IV), respectively, both S2PtNCl planes generating a dihedral angle of approximately 156°. There is no metal–metal bonding.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1023/A:1021738921514
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