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    Electronic Resource
    Electronic Resource
    Epimination of olefins by means of 3,3-pentamethyleneoxaziridine — A one-step synthesis of aziridines (1974)
    Springer
    Chemistry of heterocyclic compounds 10 (1974), S. 1432-1439 
    Details
    ISSN: 1573-8353
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Notes: Abstract 3,3-Pentamethyleneoxaziridine, which is readily obtained by treatment of cyclohexanone with ammonia and sodium hypochlorite or hydroxylamine-O-sulfonic acid, reacts with olefins with transfer of the NH group to give aziridines. Aziridines were obtained from styrene, ring- or side-chain-substituted styrenes, norbornene, and acrylonitrile in 20–70% yields. Cyclohexene is doubly aminated to give N-aminoaziridine. Nitriles are formed from phenylacetylene and diphenylacetylene as a result of rearrangement.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1007/BF00474323
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