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  • 1
    Electronic Resource
    Electronic Resource
    New York, NY [u.a.] : Wiley-Blackwell
    Journal of Applied Polymer Science 19 (1975), S. 1297-1315 
    ISSN: 0021-8995
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: A detailed mechanism and corresponding mathematical model is suggested for bulk PVC production. The model is more detailed and general than earlier models and is consistent with reported experimental data as well as new experimental evidence presented here. Equations are presented and computations performed showing the evolution of the particle size distribution of the polymer beads. The predicted particle size distributions are in reasonable agreement with the limited experimental data available.
    Additional Material: 6 Ill.
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    Bognor Regis [u.a.] : Wiley-Blackwell
    Journal of Polymer Science Part B: Polymer Physics 28 (1990), S. 763-773 
    ISSN: 0887-6266
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Notes: The dielectric permittivity and loss of poly(vinyl pyrrolidone), molecular weight 40,000, containing 40% (by weight) water have been measured over the temperature range 77-325 K and frequency range 12 Hz to 0.1 MHz. A prominent relaxation due to rotational diffusion of water molecules in a hydrogen-bonded structure occurs at T 〈 Tg (237 K). The half-width of the dipolar relaxation spectra is 2.27 decades and is temperature independent, which is strikingly different from the corresponding features of pure polymers. It is concluded that H-bonded amorphous solid water persists in the glassy polymer matrix and that the H-bonded structure contains the pyrrolidone side groups of the randomly oriented chain. The relaxation peak at T near Tg is masked by a large dc conductivity which, when expressed in terms of electric modulus, has a spectrum of half-width 1.37 instead of 1.14 decades expected for dc conductivity alone. The contribution from dipolar reorientation in the glass-rubber range of the PVP-H2O solution is smaller than that in its sub-Tg relaxation.
    Additional Material: 6 Ill.
    Type of Medium: Electronic Resource
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