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  • 1
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Berichte der deutschen chemischen Gesellschaft 127 (1994), S. 1327-1329 
    ISSN: 0009-2940
    Keywords: Macrocyclic thioethers ; Adamantane as a building block ; Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: 4,6:12,14-Di(1,3-adamantano)-1,9-dithiacyclohexadecane (1), 4,6:12,14:20,22-tri(1,3-adamantano)-1,9,17-trithiacyclotetracosane (2), and 5,7:14,16-di(1,3-adamantano)-1,2,10,11-tetrathiacyclooctadecane (3) have been obtained by intermolecular cyclization of 1,3-bis(2-bromoethyl)adamantane (4) with thioacetamide using a high-dilution technique. The reaction is concentration-dependent. The crystal structures of 1, 2, and 3 have been determined by single-crystal X-ray diffraction.
    Additional Material: 3 Ill.
    Type of Medium: Electronic Resource
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