ALBERT

Notes: Epitaxial Fe3−xSi1+x films have been grown on Si(111) by codeposition at room temperature. Their structural and electronic properties have been investigated by means of low-energy electron diffraction (LEED), x-ray photoelectron diffraction (XPD), and x-ray photoemission spectroscopy (XPS). These films, with compositions ranging from Fe3Si to FeSi, exhibit a (1×1) LEED pattern. Both XPD and core level binding energy measurements indicate that single Fe3−xSi1+x phases (with 0〈x〈1), without bulk counterpart, can be stabilized by epitaxy on Si(111). The XPD experiment clearly shows that these Fe3−xSi1+x (0≤x≤1) films adopt the same cubic structure. Furthermore, the Si 2p, Fe 2p3/2, and Fe 3s core levels are slightly shifted to higher binding energies resulting from chemical effects and differences in local coordination when going from Fe3Si (DO3) to FeSi (CsCl). Multiplet splittings ΔE3s are observed in Fe 3s core-level XPS spectra for all Fe3−xSi1+x compounds except the FeSi (CsCl) one. © 1995 American Institute of Physics.

Notes: The design and construction of a nanoelectrospray ion source for a triple quadrupole mass spectrometer that is used for identification and analysis of minimum peptide amounts is described. This interface exhibits several improvements over commercially available devices: a new capillary holder that allows very simple loading and placement of the spray capillary, and a rotary stage that enables reproducible adjustment of the capillary's angle at the orifice of the mass spectrometer. We also introduced a pressure-regulating system for fast and reproducible adjustment of the static backing air pressure onto the sample solution in the spray capillary. Furthermore, an electric safety circuit increases handling and operation safety of the nanoelectrospray interface. © 1999 American Institute of Physics.

Notes: The resistivity and residual resistance ratio of 31-nm films of AuIn2+δ have been measured for a series of precision vacuum-deposited films covering the range of −0.04≤δ≤0.12. Both the resistivity and the resistance ratio exhibit a strongly peaked dependence on δ around δ=0. The results are analyzed in terms of the Mayadas–Shatzkes theory of scattering in thin films which includes the effects of both surface and grain boundary scattering. The dominant contribution to the resistivity is due to grain boundary scattering. The grain boundary scattering coefficient is unusually large compared to published results on single-phase metal films. These findings are interpreted in relation to the structure of the films and to the presence of second-phase material (AuIn or In) in the grain boundaries.

Notes: Pseudomorphic Ga1−xInxN/GaN single heterostructures in the composition range 0〈x〈0.2 have been investigated by photoreflectance and photoluminescence spectroscopy. Strong Franz–Keldysh oscillations near the band gap of the ternary film are observed and attributed to a large constant piezoelectric field of up to 0.63 MV/cm. This allows an accurate determination of the electric field. A significant redshift between the optical band gap from photoreflectance and the luminescence maximum is observed. Luminescence is proposed to originate in the indirect transitions between the electric field tilted band edges in GaInN. The presence of this field is expected to dominate the bandstructure and the recombination and transport processes in strained nitride structures. We find no evidence for large inhomogeneities or phase separation in this material. © 1999 American Institute of Physics.

Notes: The structures of [001] tilt boundaries in silicon have been systematically investigated by computer modeling, using the harmonic Keating potential to describe the interatomic forces. The full angular range of symmetrical tilt boundaries can be described in terms of linear combinations of characteristic groupings of atoms. More than one stable relaxed structure has been found for most grain boundaries. In all cases the relaxed bicrystal consists of localized groups of pure edge or 45° dislocation cores embedded in a tetrahedrally coordinated, stable structure.

Notes: We report attaining Ga-terminated (4×2) surface reconstruction on virgin GaAs substrates using a completely dry process at temperatures below the oxide sublimation temperature and without group V overpressure. The native oxides are removed with an electron cyclotron resonance hydrogen plasma treatment, followed by annealing at 500 °C in ultrahigh vacuum, which yields a reconstructed surface suitable for epitaxial overgrowth. Characterization by secondary ion mass spectroscopy and transmission electron microscopy reveals the complete removal of O, reduced C, and high structural order at the epilayer/substrate interface when this preparation method is used before molecular beam epitaxy. Annealing the substrate at a lower temperature yields a nonreconstructed surface possessing significant impurity concentrations, and leads to dislocation defects at the epilayer/substrate interface.

Notes: Microwave detection of the Shubnikov–de Haas (SdH) effect as a contact-free characterization technique for different types of two-dimensional semiconductor structures is explored in the low magnetic field region. The detection technique and the data analysis are described. The character and relevance of the single-particle relaxation time that can be detected by this technique are distinguished from the usual transport scattering time. The measured values of the carrier concentration and single-particle relaxation time agree with electrical measurements, while the problem of making contacts on the structure is avoided. Uncertainties in the analysis for the single-particle relaxation time are discussed. Cyclotron resonance, optically detected cyclotron resonance, and magneto-photoluminescence are applied as other contact-free techniques on the same samples. The results and suitability of these techniques are compared with the microwave detection of the SdH effect.

Notes: InN has been expected to be a suitable material for electronic devices such as high mobility transistors because of its small effective mass compared to other nitrides. Heteroepitaxial InN films were grown by metalorganic vapor-phase epitaxy. The films have been structurally characterized by triple-axis x-ray diffraction (XRD) analysis in terms of lattice-mismatch dependence and InN film thickness dependence, and Hall measurements have been performed. In the XRD measurement, ω and ω–2θ scans were used, and the degree of tilting (the linewidth of x-ray signal, Δωc) [(0002) reflection] and that of twisting (Δωa) [(101¯0) reflection] have been separated. In addition, the degree of distribution of lattice constant c (Δ2θc) [(0002) reflection] of InN films has been assessed. For study of the lattice-mismatch dependence, growth of InN films on GaN, AlN and directly on sapphire substrates was performed, and accordingly, Δωc was found to range from about 500 to 4000 arcsec, and Δ2θc from about 400 to 700 arcsec. Among those three kinds of samples, InN films grown on GaN showed the smallest Δωc and Δ2θc values. Observation of c- and a-lattice parameters has shown that the InN on GaN is affected by the residual strain. On the other hand, InN thickness dependence of XRD showed that Δωc was changed from about 700 to 500 arcsec, and Δ2θc from about 600 to 300 arcsec with increasing InN thickness from 400 to 2400 Å. In accordance with the thickness of InN, Δωa was found to change from about 2500 to 1700 arcsec. Moreover, it was found that the InN film less than 1200 Å thick is composed of grain islands with different crystalline orientation and that the growth mode changes at a thickness of about 1200 Å—and screw dislocations occur. It is found that the residual strain in InN films over 1200 Å thick is gradually released, resulting in almost the same orientation. This is reflected in the reduction of the mosaicity, the proceeding of relaxation and the surface morphology. Selection of GaN for the underlying layer of the InN film has been shown to lead to structural improvement of the epitaxial InN film. In fact, InN film with a thickness of 2400 Å grown on GaN has a Hall mobility of about 700 cm2/V s even at an electron carrier concentration of 5×1019 cm−3. This value corresponds to that for GaAs at the same impurity concentration. © 1999 American Institute of Physics.

Notes: We report the 1 cm−1 resolution electron photodetachment spectra of cyanomethyl anion and its deuterated analog, trapped and detected in an ion cyclotron resonance spectrometer. Many sharp resonances were observed in the threshold region corresponding to rovibrational transitions from the ground electronic state to a dipole-supported state of the anion which subsequently undergo electron autodetachment. An assignment of the rotational transitions has been carried out, yielding rotational constants. Using spectral band intensities, we have estimated the electron binding energy of the dipole-supported state as 0.020 (±0.006) eV. The adiabatic electron affinities of the neutral radicals ⋅CH2CN and ⋅CD2CN are found to be 1.560±0.006 and 1.549±0.006 eV, respectively. Features of the dipole-supported state in this system have been compared to those in acetaldehyde enolate.

Notes: The use of an acousto-optic tunable filter spectrometer can simplify the instrumental requirements for the collection of time resolved spectra to measure the difference in absorbance of polarized radiation due to chemical functional group orientation of a polymer as it undergoes repetitive oscillatory strain. The rapid data collection achieved in the near-infrared spectral region rivals that of current interferometric instruments. Achieving a good signal to noise ratio requires only a singly modulated optical signal, and the use of digital filtering eliminates the requirement of phase sensitive detection. The usefulness of this instrument for routine testing of polymers is demonstrated by differentiating polymers of the same chemical composition but different rheology and by determining the effect of varying the concentration of monomers in a copolymer. © 2001 American Institute of Physics.