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  • 1
    Electronic Resource
    Electronic Resource
    College Park, Md. : American Institute of Physics (AIP)
    The Journal of Chemical Physics 94 (1991), S. 2509-2512 
    ISSN: 1089-7690
    Source: AIP Digital Archive
    Topics: Physics , Chemistry and Pharmacology
    Notes: The frequency of seven rovibrational transitions in the ν3 band, Q branch of 188OsO4 have been measured with high accuracy. The spectrometer used consists of two CO2 lasers [∼3 W on the 10R(0)], the first of which is stabilized on the 4.3 μm fluorescence Lamb dip of the CO2 and the second on the saturated absorption dip of the rovibrational transitions of 188OsO4. The OsO4 transition frequencies are obtained combining the known frequency of the first laser with the measured frequency of the beat note between the two laser beams. For the assignment of the transitions the recent Fourier transform analysis by Bobin et al. [J. Mol. Spectrosc. 122, 229 (1987)] was used. The access to the 10R(0) laser line has made it possible to investigate, for the first time, the Q branch of the ν3 band of OsO4 in a sub-Doppler regime. Furthermore, the tetrahedral fine structure in the ground and in the ν3 state has been analyzed using the infrared–radio frequency double resonance technique. The tetrahedral splitting constants, Dt for the ground state and Z3t for the ν3 state, have been calculated with higher accuracy than in previous works.
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    College Park, Md. : American Institute of Physics (AIP)
    The Journal of Chemical Physics 109 (1998), S. 9744-9752 
    ISSN: 1089-7690
    Source: AIP Digital Archive
    Topics: Physics , Chemistry and Pharmacology
    Notes: Thirteen new rotational transitions of H2O+ in the (0,0,0) level of the X˜ 2B1 state have been measured in the wavenumber region between 80 and 200 cm−1 (50 and 120 μm) by far-infrared laser magnetic resonance (LMR) spectroscopy. LMR data measured previously between 25 and 90 cm−1 (110 and 400 μm), as well as optical and infrared combination differences, have been combined with the new LMR data in a weighted least-squares analysis using an A-reduced expression of the rotational-fine structure Hamiltonian. Thirty-two molecular constants were simultaneously determined, some sextic centrifugal distortion parameters and some quartic and sextic spin-rotation parameters for the first time. From this improved set of molecular parameters, very accurate calculations of rotational term values and zero-field predictions of the 111–000 transition, including hyperfine structure, have been performed. Moreover, the electronic g-tensors and the hyperfine coupling constants are consistent with ab initio calculations which had been carried out for these constants. © 1998 American Institute of Physics.
    Type of Medium: Electronic Resource
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  • 3
    Electronic Resource
    Electronic Resource
    College Park, Md. : American Institute of Physics (AIP)
    The Journal of Chemical Physics 107 (1997), S. 8697-8705 
    ISSN: 1089-7690
    Source: AIP Digital Archive
    Topics: Physics , Chemistry and Pharmacology
    Notes: Atomic-force pictures reveal a heterogeneous microstructure at the surface of glassy layers which should be similar to one of the many equivalent microstructures a liquid is running through. These microstructures are described with the aid of a kinetic model of reversible aggregation which goes back to formulations as used in the description of living polymerization or aggregation of polymers in solution. Aggregates are considered as dynamic subsystems wherein collective modes of motions are excited. Fluctuations of the aggregates, densely packed in a disordered pattern, leads to a broad size distribution which happens to be controlled by Boltzmann's factor. The disordered structure within the aggregates themselves is optimized, reduced aggregate energy and entropy should be equal. Symmetries are deduced which elucidate many universal properties of the dynamic microstructure of liquids. Thermodynamic properties like the specific heats of aggregation in liquids or the dependence of the glass transition of homologues of linear atactic polystyrene are consistently described. © 1997 American Institute of Physics.
    Type of Medium: Electronic Resource
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  • 4
    Electronic Resource
    Electronic Resource
    College Park, Md. : American Institute of Physics (AIP)
    The Journal of Chemical Physics 98 (1993), S. 10049-10060 
    ISSN: 1089-7690
    Source: AIP Digital Archive
    Topics: Physics , Chemistry and Pharmacology
    Notes: The adsorption dynamics of water on NaCl(100) is studied by molecular dynamics calculations as a function of coverage. We find that, starting from a critical coverage of about 1/2 monolayer, a coupling of the water dipoles sets in and the interaction between the water molecules wins over the interaction between adsorbate and substrate leading via percolation to formation of infinite cluster networks. This effect is confirmed qualitatively by surface sensitive optical second harmonic measurements with well-controlled water exposure. At a coverage of one bilayer, a two-dimensional "ice'' structure is found to be stable. Simulated low-energy electron diffraction (LEED) patterns for this configuration are in excellent agreement with recent observation of a c(4×2) overstructure.
    Type of Medium: Electronic Resource
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  • 5
    Electronic Resource
    Electronic Resource
    College Park, Md. : American Institute of Physics (AIP)
    The Journal of Chemical Physics 96 (1992), S. 2681-2690 
    ISSN: 1089-7690
    Source: AIP Digital Archive
    Topics: Physics , Chemistry and Pharmacology
    Notes: Interference effects in electronic absorption spectra caused by coupling between excited states are calculated and interpreted by using numerical integration of the time-dependent Schrödinger equation and the time-dependent theory of electronic spectroscopy. The interference between nearby spin-forbidden doublet and spin-allowed quartet states of chromium (III) and vanadium (II) metal complexes causes sharp decreases of intensity or dips in the envelopes of absorption bands. The states are coupled by spin–orbit coupling. The origin of the dips is explained in terms of interference between wave packets moving on potential energy surfaces representing the states. The importance of curve crossing and amplitude transfer between the states is analyzed quantitatively. The theory is applied to the absorption spectrum of a chromium (III) complex.
    Type of Medium: Electronic Resource
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  • 6
    Electronic Resource
    Electronic Resource
    [S.l.] : American Institute of Physics (AIP)
    Review of Scientific Instruments 73 (2002), S. 446-452 
    ISSN: 1089-7623
    Source: AIP Digital Archive
    Topics: Physics , Electrical Engineering, Measurement and Control Technology
    Notes: A balloon-borne mass spectrometer system has been flown successfully to determine the chemical composition of polar stratospheric aerosols over northern Scandinavia. The experiment combines an aerodynamic lens which collimates the aerosols into a narrow beam, a small sphere in which they evaporate, and a mass spectrometer for gas analysis. High-speed differential pumping by two liquid helium pumps effectively lowers the presence of ambient gases without affecting the particles of the beam. Field measurements and aerosol studies inside a large cryo-chamber have shown that the concept of particle focusing, evaporation and subsequent mass spectrometric gas analysis is a reliable technique to determine the molecular composition of aerosols especially in polar stratospheric clouds. © 2002 American Institute of Physics.
    Type of Medium: Electronic Resource
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  • 7
    Electronic Resource
    Electronic Resource
    [S.l.] : American Institute of Physics (AIP)
    Review of Scientific Instruments 73 (2002), S. 1841-1844 
    ISSN: 1089-7623
    Source: AIP Digital Archive
    Topics: Physics , Electrical Engineering, Measurement and Control Technology
    Notes: Si–N based membrane calorimeters are a promising technology for the study of thermal properties of small quantities of materials in both pulsed and steady-state magnetic fields to 60 T and beyond. We present results that demonstrate our ability to measure the heat capacity of thin film samples from 2–300 K in steady-state fields up to 8 T. These measurements include the magnetoresistance of the Pt and Nb–Si thermometers and focus on confirming that the thermal conductance of the Si–N membrane does not change significantly in magnetic fields. This means the thermal conductance needs to be measured only in zero field, reducing the measurement time in high field. This is particularly important for future measurements in fields up to 60 T. © 2002 American Institute of Physics.
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  • 8
    Electronic Resource
    Electronic Resource
    Woodbury, NY : American Institute of Physics (AIP)
    Applied Physics Letters 53 (1988), S. 1705-1707 
    ISSN: 1077-3118
    Source: AIP Digital Archive
    Topics: Physics
    Notes: Photolysis of CpPt(Me)3(Cp=η5-C5H5, Me=CH3) at room temperature and atmospheric pressure produces thin films and patterned structures of platinum metal on solid substrates. The platinum films are characterized by Auger electron spectroscopy, x-ray diffraction, and scanning electron microscopy. Substrates can also be prepatterned by laser irradiation and then developed into a shiny platinum deposit at a later time.
    Type of Medium: Electronic Resource
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  • 9
    Electronic Resource
    Electronic Resource
    Woodbury, NY : American Institute of Physics (AIP)
    Applied Physics Letters 60 (1992), S. 1402-1403 
    ISSN: 1077-3118
    Source: AIP Digital Archive
    Topics: Physics
    Notes: High purity (less than 1% carbon) thin films of rhodium and iridium metal have been obtained by laser-assisted organometallic chemical vapor deposition. Gaseous (η5-C5H5)M(C2H4)2 (M=Rh,Ir) was the organometallic precursor. Depositions were carried out in an atmosphere of He and H2 at room temperature and atmospheric pressure. Wavelength dependence studies of the rhodium precursor have shown that only irradiation into the compound's charge transfer band causes deposition. Deposits can also be obtained thermally. The films were analyzed by x-ray diffraction and x-ray photoelectron spectroscopy.
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  • 10
    Electronic Resource
    Electronic Resource
    College Park, Md. : American Institute of Physics (AIP)
    The Journal of Chemical Physics 84 (1986), S. 1935-1937 
    ISSN: 1089-7690
    Source: AIP Digital Archive
    Topics: Physics , Chemistry and Pharmacology
    Notes: The rotational spectrum of MgH in its ground 2∑ state has been observed for the first time using a new tunable far infrared spectrometer. The molecular constants derived are of sufficient accuracy to permit astrophysical identification of this species.
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