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  • GEOPHYSICS  (184)
  • Chemical Engineering  (59)
  • 1980-1984  (243)
  • 1981  (243)
  • 1
    Publication Date: 2019-06-28
    Description: Increased understanding of the chemical phenomena occurring in the troposphere was the research goal. Emphasis was placed on tropospheric impact on environmental quality, including public health, agriculture, climate, and weather.
    Keywords: GEOPHYSICS
    Type: NASA-RP-1062 , L-13855
    Format: application/pdf
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  • 2
    Publication Date: 2019-06-28
    Description: Theoretical calculations are presented which estimate the possible magnitude of the O3/H2O derived OH interference signal resulting from the use of the laser-induced fluorescence technique in measuring natural levels of tropospheric OH. Critical to this new assessment has been the measurement of the nascent OH quantum state distribution resulting from the reaction O(1D) + H2O yields 2OH, and an assessment of the subsequent rotational relaxation of the OH species when formed in high k levels.
    Keywords: GEOPHYSICS
    Type: Geophysical Research Letters; 8; Jan. 198
    Format: text
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  • 3
    Publication Date: 2019-07-13
    Description: Solar radiation measurements are made on a routine basis. Global solar, atmospheric emitted, downwelled diffuse solar, and direct solar radiation measurement systems are fully operational with the first two in continuous operation. Fractional cloud cover measurements are made from GOES imagery or from ground based whole sky photographs. Normalized global solar irradiance values for partly cloudy skies were correlated to fractional cloud cover.
    Keywords: GEOPHYSICS
    Type: NASA-CR-164694
    Format: application/pdf
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  • 4
    Electronic Resource
    Electronic Resource
    Stamford, Conn. [u.a.] : Wiley-Blackwell
    Polymer Engineering and Science 21 (1981), S. 39-46 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Thermoplastic interpenetrating polymer networks, IPN's, are defined as combinations of two physically crosslinked polymers. A styrene-b-ethylene-co-butylene-b-styrene (SEBS) triblock elastomer was combined with an ionomer prepared from a random copolymer of styrene, methacrylic acid, and isoprene (90/10/1 by volume), and subsequently neutralized. Two subclasses of the thermoplastic IPN's were identified. A sequential polymerization method yielded the chemically blended thermoplastic IPN's (CBT IPN's). Melt blending of the separately synthesized polymers produced the mechanically blended thermoplastic IPN's (MBT IPN's). Stress-strain and Rheovibron characterization revealed that the CBT IPN's exhibited greater tensile strength and higher elongation at break, but lower moduli than the MBT IPN materials of the same overall composition. Analysis of moduli data with the theories of Takayanagi, Davies, Budiansky, and Kerner disclosed more equal dual phase continuity for the MBT IPN's than the CBT IPN's at each composition. The low modulus of the more rubbery CBT IPN compositions was attributed to a decrease in the effective chain end-to-end distance between crosslinks in the elastomeric (EB) center block, brought about by the synthetic method.
    Additional Material: 4 Ill.
    Type of Medium: Electronic Resource
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  • 5
    Electronic Resource
    Electronic Resource
    Stamford, Conn. [u.a.] : Wiley-Blackwell
    Polymer Engineering and Science 21 (1981), S. 86-92 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: An experimental investigation into the performance in general and the melting behavior in particular of a single screw extruder running with a low density polyethylene power has been carried out and the results compared with those for a granular feedstock of low density polyethylene having similar melt properties. It was found that the tendency was for the output rate, pressure generated and specific power consumption to be lower for the powders, and that the removal of barrel heating near the feed hopper increased these parameters. Two melting mechanisms were observed in powder extrusion; one being the classic “Maddock” type, and the other such that the solid bed and melt pool were in reversed positions relative to the Maddock case. There was a trend for this latter mechanism to operate with low screw speeds, shallow channels and full heating. Melt initiation occurred nearer the feed end and melting was completed much more quickly with powders. An explanation of the mechanisms is proposed which is based on the observation of early melt initiation, and the industrial practices of feed zone cooling and increasing feed pressure generation to improve the performance of extruders running with powders are seen to be consistent with this proposition.
    Additional Material: 7 Ill.
    Type of Medium: Electronic Resource
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  • 6
    Electronic Resource
    Electronic Resource
    Stamford, Conn. [u.a.] : Wiley-Blackwell
    Polymer Engineering and Science 21 (1981), S. 1173-1180 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: The tensile fatigue behavior of unnotched injection molded polysulfone specimens has been investigated. The effects of orientation and residual stress were studied by comparing asmolded specimens with annealed or annealed and quenched specimens with a known residual stress pattern. The treatments are shown to have differing effects at high stresses, where failure is by shear yielding and necking, and at intermediate stresses, where failure is by fatigue crack propagation. The geometries of fatigue cracks are described for each case. An attempt is made to separate the effects of crack and craze initiation from crack propagation, and cyclic loading from cumulative time under load.
    Additional Material: 8 Ill.
    Type of Medium: Electronic Resource
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  • 7
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 27 (1981), S. 226-234 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: The effect of varying pore structures on the kinetics of fluid-solid reactions is investigated through the random pore model developed in prior papers (Bhatia and Perlmutter, 1980, 1981). By considering several idealized pore-size distributions it is shown that a solid having a uniform pore size is intrinsically less reactive than one possessing a pore-size distribution. For solids with bimodal pore size distributions optimal structures are shown to exist for which the reactivity is a maximum.Numerical solutions were obtained to the model equations for various values of the parameters characterizing the pore structure, the diffusion, and the chemical kinetics. The results show that the conversion-time behavior and the expected ultimate conversion can be very sensitive to variations in surface area and porosity for reactions accompanied by an increase in volume of the solid phase.These findings are in agreement with experimental literature on the SO2-lime reaction (Ulerich et al., 1978; Borgwardt and Harvey, 1972; Potter, 1969; Falkenberry and Slack, 1968) and the model is shown to fit the data of Borgwardt (1970), and of Hartman and Coughlin (1974, 1976). It is seen that this reaction is diffusion controlled under the conditions of Hartman and Coughlin, in consonance with their own finding using the grain model, and a prior Pigford and Sliger (1973) interpretation. The temperature behavior of the diffusion coefficient in the product layer suggests the participation of an activated process, possibly a solid state diffusion step.
    Additional Material: 11 Ill.
    Type of Medium: Electronic Resource
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  • 8
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 27 (1981), S. 975-984 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Filtration of carbon black particles from tetralin through a bed of sand with simultaneous measurement of bed streaming potential shows that the charge on the filter and its neutralization by depositing colloidal particles plays an important role in filter performance. Filter capacities up to the point of charge neutralization, calculated from knowledge of the colloid and filter zeta potentials using a semitheoretical model for variation of filter surface charge characteristics, are found to be in good agreement with experimental values.
    Additional Material: 11 Ill.
    Type of Medium: Electronic Resource
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  • 9
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 27 (1981), S. 920-927 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: A series of seven coals were oxidized in a fixed bed reactor to determine the controlling reaction regimes during mild coal oxidation. The effects of coal porosity and particle size, reactor temperature, and oxygen partial pressure were evaluated. The results show that coal-oxygen reactions are controlled by the rate of internal gaseous diffusion for most coals, and by the rate of chemical reaction for the most porous coal of the set tested. Particle size effects also suggest internal diffusional control. Determinations of cumulative oxygen deposition indicate that surface areas several orders of magnitude greater than the superficial surface can participate in oxidation reactions, putting in doubt the applicability of the model previously derived by Kam et al. (1976a) for external mass transfer control.
    Additional Material: 12 Ill.
    Type of Medium: Electronic Resource
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  • 10
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 27 (1981), S. 203-207 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: A new static cell for vapor-liquid equilibria up to 100 MPa between 233 and 433 K is presented. A detachable sampling microcell and a special chromatographic injector are used in a new sampling system suitable for gas chromatographic analysis of mixtures with high boiling components. The test system is N2 - n-Heptane at 305.45 K.
    Additional Material: 5 Ill.
    Type of Medium: Electronic Resource
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