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  • 1
    ISSN: 1089-7550
    Source: AIP Digital Archive
    Topics: Physics
    Notes: Layered structures of cubic yttria-stabilized zirconia (YSZ) sandwiched between two layers of platinum/YSZ composites with the platinum concentration varying between 20 and 55 vol % were prepared. Large double-layer capacitances were obtained due to the presence of large three-dimensional electrode surface areas in the composite layers. The layers were subjected to image analysis obtained from scanning electron microscopy micrographs. The specific surface area of the platinum particles decreased from ∼17×103 to ∼13.5×103 cm2/cm3 with increasing Pt concentration. Image analyses obtained with an in-lens detector revealed that the effective surface area of the Pt particles that were part of a conducting percolative network increased with Pt concentration to ca. 11×103 cm2/cm3 at a Pt metal volume fraction of 0.50. Impedance spectroscopy measurements performed at 550 °C demonstrated that the capacitance increased with increasing Pt concentration in the composite layer and optimal values as high as 4.3±1.3 kF/m2 at 50 vol % Pt were recorded. The specific electrode surface area calculated from this data was in good agreement with the data obtained from image analysis. © 2001 American Institute of Physics.
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    Oxford, UK : Blackwell Science Ltd
    Grass and forage science 60 (2005), S. 0 
    ISSN: 1365-2494
    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Agriculture, Forestry, Horticulture, Fishery, Domestic Science, Nutrition
    Notes: The use of imaging spectroscopy to predict the herbage mass of dry matter (DM), DM content of herbage and crude fibre, ash, total sugars and mineral (N, P, K, S, Ca, Mg, Mn, Zn and Fe) concentrations was evaluated. The experimental system used measured reflectance between 404 and 1650 nm at high spatial (0·28–1·45 mm2) and spectral resolution. Data from two experiments with Lolium perenne L. mini-swards were used where the degree of sward damage or N-fertilizer application varied. Regression models were calibrated and validated and the potential reduction in prediction error with multiple observations was estimated. The mean prediction errors for DM mass, DM content and N, total sugars, ash and crude fibre concentrations were 235–268 kg ha−1, 9·6–16·8 g kg−1, 2·4–3·4 g kg DM−1, 16·2–27·7 g kg DM−1, 5·8–6·5 g kg DM−1 and 8·4–10·4 g kg DM−1 respectively. The predictions for concentrations of P, K, S and Mg allowed identification of deficiency levels, in contrast to the concentrations of Na, Zn, Mn and Ca which could not be predicted with adequate precision. Prediction errors of DM mass may be maximally reduced to 95–142 kg ha−1 with 25 replicate measurements per field. It is concluded that imaging spectroscopy can provide an accurate means for assessment of DM mass of standing grass herbage. Predictions of macronutrient content and feeding value were satisfactory. The methodology requires further evaluation under field conditions.
    Type of Medium: Electronic Resource
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  • 3
    Electronic Resource
    Electronic Resource
    [S.l.] : American Institute of Physics (AIP)
    Journal of Applied Physics 60 (1986), S. 2543-2547 
    ISSN: 1089-7550
    Source: AIP Digital Archive
    Topics: Physics
    Notes: The anneal behavior of plasma-enhanced chemical vapor deposited silicon oxynitride films has been studied using Fourier transform infrared absorption spectroscopy, nuclear reaction analysis, and electron-spin resonance. The anneal temperature range was 500–1000 °C. It is observed that the oxynitrides which contain only N–H bonds are thermally stable in the temperature range under study. The layers which also contain Si–H bonds are considerably less thermally stable. Abundant hydrogen effusion from these layers is observed at temperatures as low as 600 °C, accompanied by cracking and shrinkage of the films. It is suggested that the coexistence of both Si–H and N–H bonds offers the possibility for cross linking and that consequently the decomposition temperature of both types of bonds is lowered. Evidence for the occurrence of cross linking is found in the infrared difference spectra. Consistently, the silicon unpaired electron density does not increase upon annealing. The Si–H and N–H bands effectively shift towards higher wave numbers upon annealing at higher temperatures. This is ascribed to the inhomogeneity in bond strength, which in turn is related to a variation in electronegativity of the surrounding groups.
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  • 4
    Electronic Resource
    Electronic Resource
    [S.l.] : American Institute of Physics (AIP)
    Journal of Applied Physics 60 (1986), S. 2536-2542 
    ISSN: 1089-7550
    Source: AIP Digital Archive
    Topics: Physics
    Notes: Silicon oxynitride films with varying oxygen/nitrogen ratio were grown from SiH4, N2O, and NH3 by means of a plasma-enchanced chemical vapor deposition process. The elemental composition of the deposited films was measured by a variety of high-energy ion beam techniques. To determine the chemical structure we used Fourier transform infrared absorption spectroscopy and electron-spin resonance. Ellipsometric data and values for mechanical stress are also reported. We show that the entire range of compositions from silicon oxide to silicon nitride can be covered by applying two different processes and by adjusting the N2O/NH3 gas flow ratio of the respective processes. It is suggested that the N2O/SiH4 gas flow ratio is the major deposition characterization parameter, which also controls the chemical structure as far as the hydrogen bonding configuration is concerned. We found that the films contain significant amounts of excess silicon and that the mechanical stress in the oxynitrides is lower than in plasma nitride. The electron-spin density is low (∼1017/cm3) in all samples.
    Type of Medium: Electronic Resource
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  • 5
    Electronic Resource
    Electronic Resource
    Woodbury, NY : American Institute of Physics (AIP)
    Applied Physics Letters 57 (1990), S. 2704-2706 
    ISSN: 1077-3118
    Source: AIP Digital Archive
    Topics: Physics
    Notes: Polycrystalline silicon wafers have been subjected to annealing (700 °C, 1 h) and to a hydrogen plasma (350 °C, 30 min) during the processing of solar cells. The annealing treatment enhances the bulk minority-carrier recombination lifetime by 19%, presumably by impurity gettering. The plasma treatment improves the lifetime by 26%; hydrogen passivation accounts for at least 2/3 of this improvement. Gettering and passivation are found to be complementary: application of both treatments results in a 43% increase in lifetime compared to standard.
    Type of Medium: Electronic Resource
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  • 6
    Electronic Resource
    Electronic Resource
    Amsterdam : Elsevier
    Microelectronic Engineering 25 (1994), S. 185-200 
    ISSN: 0167-9317
    Source: Elsevier Journal Backfiles on ScienceDirect 1907 - 2002
    Topics: Electrical Engineering, Measurement and Control Technology
    Type of Medium: Electronic Resource
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  • 7
    Electronic Resource
    Electronic Resource
    Amsterdam : Elsevier
    Tetrahedron Letters 6 (1965), S. 903 
    ISSN: 0040-4039
    Source: Elsevier Journal Backfiles on ScienceDirect 1907 - 2002
    Topics: Chemistry and Pharmacology
    Type of Medium: Electronic Resource
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  • 8
    Electronic Resource
    Electronic Resource
    Amsterdam : Elsevier
    Thin Solid Films 113 (1984), S. 59-72 
    ISSN: 0040-6090
    Source: Elsevier Journal Backfiles on ScienceDirect 1907 - 2002
    Topics: Physics
    Type of Medium: Electronic Resource
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  • 9
    ISSN: 1573-4838
    Source: Springer Online Journal Archives 1860-2000
    Topics: Medicine , Technology
    Notes: Surface analysis techniques have been used to characterize heparin-containing bioactive coatings. The relationship between uncoated polymer, intermediate coupling and final layer surface chemistry upon the overall quality of the coating system has been investigated. The results present data from ToFSIMS, XPS and bioactivity in terms of thrombin deactivation as measured using chromogenic assay technique on heparin-based coatings on polymer surfaces including LDPE and PVC. The effect of pretreatment of uncoated polymer surfaces has been investigated where a number of effects critical to coating performance have been identified. Studies of the intermediate coupling regime show how the first and final stages of coupling are the most critical. Finally it is shown how the integrity, mean thickness and chemical state of the heparin final layer can be measured using a combination of ToFSIMS and XPS.
    Type of Medium: Electronic Resource
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  • 10
    ISSN: 1573-4838
    Source: Springer Online Journal Archives 1860-2000
    Topics: Medicine , Technology
    Notes: One of the major clinical complications in the biomedical application of synthetic materials is the incidence of implant-associated infections. Such infections are very often induced by Staphylococcus aureus. To obtain information on tissue reactions and minimal bacterial challenge needed to create an infection related to untreated implant surfaces, we injected polyurethane tubing segments with a series of Staphylococcus aureus. The segments were subcutaneously implanted in rats. Implantation periods varied from 2, 5 and 10 days to 3 weeks. Specimen were evaluated using light and transmission electron microscopy. At least 0.25×104 of Staphylococci aureus were needed to clearly recognize that bacteria had been injected in the polyurethane tubing segments. The evidence was indirect, showing high infiltration and activation of neutrophils and macrophages, but not bacteria. Furthermore, 0.25×106 S. aureus were needed to induce a persistent specific inflammatory reaction with high concentrations of lymphocytes, i.e. mainly plasma-cells, at 3 weeks. The results indicate that this model functioned well to obtain the wanted information. Results are discussed with respect to (a-) specific inflammatory reactions occurring with (bacterial-challenged) biomaterials. Ultimately, our goal is to develop infection-resistant materials, for which the in vivo model developed may be used to qualify the processed materials
    Type of Medium: Electronic Resource
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