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  • Analytical Chemistry and Spectroscopy  (1)
  • Neumann series  (1)
  • 1990-1994  (2)
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  • 1990-1994  (2)
Year
  • 1
    Electronic Resource
    Electronic Resource
    New York, NY : Wiley-Blackwell
    Rapid Communications in Mass Spectrometry 7 (1993), S. 99-105 
    ISSN: 0951-4198
    Keywords: Chemistry ; Analytical Chemistry and Spectroscopy
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Physics
    Notes: New methods are presented for the evaluation of ion structures and fragmentation pathways using tandem mass spectrometry (MS/MS) with low energy collision-induced dissociation. As an aid for mass spectroscopists, they incorporate a PC software package (named PDNL, written in Turbo-PASCAL 5.5 (Borland), running under DOS (Microsoft) with mouse-control). A database of almost 300 low energy MS/MS spetra is available for library searches. It utilizes a new, intensity-based matching algorithm fitting to the demand of MS/MS data. Computational methods have been developed for (i) the separation of the spectra of unresolved isobaric ions and evaluation of the ratio of the ion abundances, (ii) the evaluation of single-collision spectra using the multi-collisional data map, and (iii) the elucidation of collision-induced dissociation fragmentation pathways. Principal component analyses of sets of at least eight MS/MS spectra were used for a quick comparison of these spectra and for a summary of inter-ion relationships.
    Additional Material: 6 Ill.
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    Springer
    Numerical algorithms 3 (1992), S. 235-244 
    ISSN: 1572-9265
    Keywords: AMS 65D ; 33C ; Neumann series ; Bessel functions ; Padé approximation
    Source: Springer Online Journal Archives 1860-2000
    Topics: Computer Science , Mathematics
    Notes: Abstract LetJ n (z) be the Bessel function of the first kind and ordern, and letf(z) be an analytic function in|z|≤r (r〉0); then it is known that the Bessel expansion $$f(z) = \sum\limits_{n = 0}^\infty {a_n J_n (z) (Neumann series)} $$ converges for|z|≤r. In this paper, we shall be concerned with the construction of “approximating” functions to (1) which are easily computable (rational functions). Namely, making use of the generating function for the family {J n (z)}, a rational functionf k (z) with prescribed poles can be obtained such thatf k (z) “approximates” tof(z) in the following sense: $$f_k (z) = \sum\limits_{n = 0}^\infty {\bar a_n J_n (z)} with \bar a_n = a_n , n = 0,1,...,k - 1;$$ and it will be said thatf k is an “approximant” of orderk. When orthogonality conditions with respect to a linear functional defined from the sequence {a n} are used, then the order of approximation may be increased up to2k. An algebraic approach of these approximants is carried out.
    Type of Medium: Electronic Resource
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