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  • 1
    Keywords: Chemicals ; Safety measures ; Chemistry, Physical organic ; Crystallography ; Materials ; Thermodynamics
    ISBN: 9783540681519
    Language: English
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  • 2
    Unknown
    Tokyo : TERRAPUB
    Keywords: shock compression ; fundamentals of shock wave propagation ; shock compression technology ; thermomechanics of powder compaction and mass mixing ; thermochemistry of heterogeneous mixtures ; hydrodynamical calculations ; shock conditioning and processing of ceramics
    Description / Table of Contents: INTRODUCTION --- Shock Compression Chemistry of materials, Y. Horie and A. B. Sawaoka, pp. 3-22 --- 1.1 The Nature of Shock Waves, pp. 3-5 --- 1.2 Compaction of Powders and Shock Activation, pp. 6-9 --- 1.3 First-Order Phase Transitions and Chemical Reactions, pp. 10-12 --- 1.4 Time Scales and Interactions of Basic Mechanisms, p. 12 --- 1.4.1 Shock propagation in a particle assemblage, p. 12 --- 1.4.2 Energy localization, pp. 12-13 --- 1.4.3 Thermal relaxation of hot spots, p. 14 --- 1.4.4 Mass diffusion in solids, p. 14 --- 1.4.5 Kinetic constants, pp. 14-16 --- 1.5 Some Roles of Shock Compression Techniques in Material Sciences Study, p. 16 --- 1.5.1 Shock compression technique as a tool of high pressure production, p. 16 --- 1.5.2 Appearance of diamond anvil-type high-pressure apparatus, pp. 16-18 --- 1.5.3 New roles of shock compression technology as a unique method of very high temperature production, pp. 18-19 --- 1.5.4 Development of conventional hypervelocity impact techniques for precise measurement of materials under shock compression, pp. 19-21 --- FUNDAMENTALS OF SHOCK WAVE PROPAGATION --- Shock Compression Chemistry of materials, Y. Horie and A. B. Sawaoka, pp. 23-78 --- 2.1 Hydrodynamic Jump Conditions and the Hugoniot Curve, pp. 23-32 --- 2.2 Shock Transition in Hydrodynamic Solids, pp. 32-42 --- 2.3 Non-Hydrostatic Deformation of Solids, p. 42 --- 2.3.1 Elastic-ideally-plastic solids, pp. 42-53 --- 2.3.2 Experimental observations of elastic-plastic behavior, pp. 53-56 --- 2.4 Wave-body interactions, pp. 56-57 --- 2.4.1 Preliminaries, pp. 57-60 --- 2.4.2 Planar impact of similar and dissimilar bodies, pp. 60-61 --- 2.4.3 Shock wave interaction with material boundaries, pp. 61-64 --- 2.4.4 Wave-wave interactions, pp. 65-66 --- 2.4.5 Detonation wave and interaction with a solid surface, pp. 66-77 --- SHOCK COMPRESSION TECHNOLOGY --- Shock Compression Chemistry of materials, Y. Horie and A. B. Sawaoka, pp. 79-115 --- 3.1 Gun Techniques, p. 80 --- 3.1.1 Single stage gun, p. 80 --- 3.1.2 Conventional two stage light gas gun, pp. 80-83 --- 3.1.3 Velocity measurement of projectile, p. 83 --- 3.1.4 Magnetoflyer method, pp. 83-84 --- 3.1.5 CW x-ray velocity meter, pp. 84-86 --- 3.1.6 Measurement of interior projectile motion, pp. 86-87 --- 3.1.7 Recovery experiments, pp. 87-89 --- 3.2 Explosive Techniques, p. 89 --- 3.2.1 Plane shock wave generation and recovery fixture, pp. 89-91 --- 3.2.2 Numerical simulaation of shock compression in the recovery capsule, pp. 91-94 --- 3.2.3 Cylindrical recovery fixture, pp. 94-95 --- 3.3 In-situ Measurements, p. 95 --- 3.3.1 Manganin pressure gauge, pp. 95-98 --- 3.3.2 Particle velocity gauge, pp. 99-100 --- 3.3.3 Observations of multiple shock reverberations by using a manganin pressure gauge and particle velocity gauge, pp. 100-106 --- 3.3.4 Shock temperature measurement, pp. 106-111 --- 3.3.5 Copper-Constantan thermocouple as a temperature and pressure gauge, pp. 111-113 --- THERMOMECHANICS OF POWDER COMPACTION AND MASS MIXING --- Shock Compression Chemistry of materials, Y. Horie and A. B. Sawaoka, pp. 117-170 --- 4.1 A One Dimensional Particulate Model, pp. 117-123 --- 4.2 Continuum Models, p. 123 --- 4.2.1 Hydrodynamic models, pp. 124-141 --- 4.2.2 Continuum plasticity theory, pp. 141-148 --- 4.2.3 Application, pp. 148-154 --- 4.3 Particle Bonding and Heterogeneous Processes, pp. 154-160 --- 4.4 Mass Mixing, pp. 160-169 --- THERMOCHEMISTRY OF HETEROGENEOUS MIXTURES --- Shock Compression Chemistry of materials, Y. Horie and A. B. Sawaoka, pp. 171-225 --- 5.1 Thermodynamic Functions of Heterogeneous Mixtures, pp. 172-187 --- 5.2 Analytical Equations of State, pp. 187-191 --- 5.3 Hugoniots of Inert Mixtures, p. 191 --- 5.3.1 Thermodynamically equilibrium models, pp. 191-197 --- 5.3.2 Mechanical models, pp. 197-199 --- 5.4 First-Order Phase Transitions, pp. 199-206 --- 5.5 Chemical Equilibria, pp. 206-212 --- 5.6 Reaction Kinetics, p. 212 --- 5.6.1 Rate equations, pp. 212-214 --- 5.6.2 Nucleation, pp. 214-216 --- 5.6.3 Growth, pp. 216-217 --- 5.6.4 Pressure effects, pp. 217-218 --- 5.7 Shock-Induced Reactions in Powder Mixtures, pp. 218-224 --- HYDRODYNAMICAL CALCULATIONS --- Shock Compression Chemistry of materials, Y. Horie and A. B. Sawaoka, pp. 227-276 --- 6.1 Conservation Equations of Continuum Flow, pp. 227-228 --- 6.1.1 Mass conservation, pp. 228-230 --- 6.1.2 Conservation of linear momentum, pp. 230-231 --- 6.1.3 Enegy conservation, pp. 231-234 --- 6.2 Constitutive Modeling of Inorganic Shock Chemistry, pp. 234-235 --- 6.2.1 VIR model, pp. 235-239 --- 6.2.2 Pore collapse, p. 239 --- 6.2.3 Chemical kinetics, pp. 239-240 --- 6.2.4 Computational constitutive reactions, pp. 240-245 --- 6.3 Applications of the VIR Model, p. 245 --- 6.3.1 Shock wave profiles in Ni/Al powder mixtures, pp. 245-250 --- 6.3.2 Compaction of diamond with Si and graphite, pp. 250-257 --- 6.4 Continuum Mixture Theory and the VIR Model, p. 257 --- 6.4.1 Continuum mixture theory, pp. 257-263 --- 6.4.2 Derivation of the VIR model using the CMT, pp. 263-269 --- 6.4.3 A model of heterogeneous flow, pp. 269-275 --- SHOCK CONDITIONING AND PROCESSING OF CERAMICS --- Shock Compression Chemistry of materials, Y. Horie and A. B. Sawaoka, pp. 277-360 --- 7.1 Shock Conditioning of Powder of Inorganic Materials, p. 227 --- 7.1.1 Brief review of shock conditioning studies, p. 227 --- 7.1.2 Aluminum oxide powder, pp. 277-281 --- 7.2 Shock Synthesis of Inorganic Materials, p. 281 --- 7.2.1 Shock synthesis studies, p. 281 --- 7.2.2 High dense forms of carbon, pp. 281-285 --- 7.2.3 High dense forms of boron nitride, pp. 285-287 --- 7.2.4 Shock treatment of boron nitride powders, pp. 287-301 --- 7.3 Shock Consolidation of Ceramic Powders, p. 301 --- 7.3.1 Why non-oxide ceramics?, pp. 301-302 --- 7.3.2 Dynamic consolidation of SiC powders, pp. 302-304 --- 7.3.3 Approach to the fabrication of crack free compacts, pp. 304-305 --- 7.3.4 Shock consolidation of SiC powder utilizing post shock heating by exothermic reaction, pp. 305-310 --- 7.4 Dynamic Compaction of Zinc Blende Type Boron Nitride and Diamond Powders, p. 310 --- 7.4.1 Background, pp. 310-311 --- 7.4.2 Cubic boron nitride, pp. 311-318 --- 7.4.3 Diamond, pp. 318-326 --- 7.4.4 Diamond composites obtained by utilizzing exothermic chemical reaction, pp. 326-332 --- 7.5 Very High Pressure Sintering of Shock Treated Powders, pp. 332-334 --- 7.5.1 Silicon nitride, pp. 334-336 --- 7.5.2 w-BN, pp. 336-346 --- 7.6 Rapid Condensation of High Temperature Ultrasupersaturated Gas, p. 346 --- 7.6.1 Silicon nitride, pp. 346-352 --- 7.6.2 Carbon, pp. 352-357
    Pages: Online-Ressource (VI, 364 Seiten)
    ISBN: 4876771073
    Language: English
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  • 3
    Publication Date: 2018-06-26
    Description: Although Aspergillus fumigatus is the major agent of invasive aspergillosis, an increasing number of infections are caused by its cryptic species, especially A. lentulus and the A. viridinutans species complex (AVSC). Their identification is clinically relevant because of antifungal drug resistance and refractory infections. Species boundaries in the AVSC are unresolved since most species have uniform morphology and produce interspecific hybrids in vitro. Clinical and environmental strains from six continents (n = 110) were characterized by DNA sequencing of four to six loci. Biological compatibilities were tested within and between major phylogenetic clades, and ascospore morphology was characterised. Species delimitation methods based on the multispecies coalescent model (MSC) supported recognition of ten species including one new species. Four species are confirmed opportunistic pathogens; A. udagawae followed by A. felis and A. pseudoviridinutans are known from opportunistic human infections, while A. felis followed by A. udagawae and A. wyomingensis are agents of feline sino-orbital aspergillosis. Recently described human-pathogenic species A. parafelis and A. pseudofelis are synonymized with A. felis and an epitype is designated for A. udagawae. Intraspecific mating assay showed that only a few of the heterothallic species can readily generate sexual morphs in vitro. Interspecific mating assays revealed that five different species combinations were biologically compatible. Hybrid ascospores had atypical surface ornamentation and significantly different dimensions compared to parental species. This suggests that species limits in the AVSC are maintained by both pre- and post-zygotic barriers and these species display a great potential for rapid adaptation and modulation of virulence. This study highlights that a sufficient number of strains representing genetic diversity within a species is essential for meaningful species boundaries delimitation in cryptic species complexes. MSC-based delimitation methods are robust and suitable tools for evaluation of boundaries between these species.
    Keywords: Aspergillus felis ; Aspergillus fumigatus ; invasive aspergillosis ; mating-type genes ; multispecies coalescence model ; Neosartorya udagawae ; scanning electron microscopy ; soil fungi
    Repository Name: National Museum of Natural History, Netherlands
    Type: Article / Letter to the editor
    Format: application/pdf
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  • 4
    Publication Date: 2024-01-12
    Description: Although Aspergillus fumigatus is the major agent of invasive aspergillosis, an increasing number of infections are caused by its cryptic species, especially A. lentulus and the A. viridinutans species complex (AVSC). Their identification is clinically relevant because of antifungal drug resistance and refractory infections. Species boundaries in the AVSC are unresolved since most species have uniform morphology and produce interspecific hybrids in vitro. Clinical and environmental strains from six continents (n = 110) were characterized by DNA sequencing of four to six loci. Biological compatibilities were tested within and between major phylogenetic clades, and ascospore morphology was characterised. Species delimitation methods based on the multispecies coalescent model (MSC) supported recognition of ten species including one new species. Four species are confirmed opportunistic pathogens; A. udagawae followed by A. felis and A. pseudoviridinutans are known from opportunistic human infections, while A. felis followed by A. udagawae and A. wyomingensis are agents of feline sino-orbital aspergillosis. Recently described human-pathogenic species A. parafelis and A. pseudofelis are synonymized with A. felis and an epitype is designated for A. udagawae. Intraspecific mating assay showed that only a few of the heterothallic species can readily generate sexual morphs in vitro. Interspecific mating assays revealed that five different species combinations were biologically compatible. Hybrid ascospores had atypical surface ornamentation and significantly different dimensions compared to parental species. This suggests that species limits in the AVSC are maintained by both pre- and post-zygotic barriers and these species display a great potential for rapid adaptation and modulation of virulence. This study highlights that a sufficient number of strains representing genetic diversity within a species is essential for meaningful species boundaries delimitation in cryptic species complexes. MSC-based delimitation methods are robust and suitable tools for evaluation of boundaries between these species.
    Keywords: Aspergillus felis ; Aspergillus fumigatus ; invasive aspergillosis ; mating-type genes ; multispecies coalescence model ; Neosartorya udagawae ; scanning electron microscopy ; soil fungi
    Repository Name: National Museum of Natural History, Netherlands
    Type: info:eu-repo/semantics/article
    Format: application/pdf
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  • 5
    Electronic Resource
    Electronic Resource
    [S.l.] : American Institute of Physics (AIP)
    Journal of Applied Physics 76 (1994), S. 3394-3402 
    ISSN: 1089-7550
    Source: AIP Digital Archive
    Topics: Physics
    Notes: An improved hydrodynamic model has been developed for analysis and interpretation of shock-induced chemical reactions in inorganic powder mixtures. Attention is focused on the interaction of hydrodynamic flow with the thermodynamic changes associated with chemical reactions such as specific volume, specific internal energy, and material properties. Predictive capabilities of the model have been illustrated using experimental shock wave profile data involving Ni-Al and Al-Fe2O3 mixtures.
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  • 6
    Electronic Resource
    Electronic Resource
    [S.l.] : American Institute of Physics (AIP)
    Journal of Applied Physics 84 (1998), S. 3574-3580 
    ISSN: 1089-7550
    Source: AIP Digital Archive
    Topics: Physics
    Notes: A two-dimensional discrete element code (DM2), was used to model a complex interplay of deformation and chemical reaction in a region of localized shear at the particle level. Two exothermic mixtures of Nb–Si and Ni–Al particles having dimensions of 5 μm×25 μm were considered. Computational experiments showed that the mixtures exhibit a classical phenomenon of thermal explosion under high rates of shearing. The threshold shear rates were found to be approximately 1.2×108/s and 8.0×107/s for the Nb–Si and Ni–Al mixtures, respectively. The ignition conditions were sensitive to the thermal boundary conditions and the computationally observed values are considered to be the upper limits. The thermal explosion results from the interaction of mechanical mass mixing and heating that were primarily caused by thinning (plastic deformation) and fragmentation. The modeling showed an interesting result: that there is a ratio of fracture strengths that maximizes the mass mixing. © 1998 American Institute of Physics.
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  • 7
    Electronic Resource
    Electronic Resource
    [S.l.] : American Institute of Physics (AIP)
    Journal of Applied Physics 84 (1998), S. 1292-1298 
    ISSN: 1089-7550
    Source: AIP Digital Archive
    Topics: Physics
    Notes: Shock-induced particle velocity dispersion in solid mixtures was numerically investigated using two approaches: discrete element simulation and continuum mixture calculation. Results show (i) a trend-wise agreement between the two models, (ii) nonequilibrium distributions of particle velocity dispersion, and (iii) particle velocity dispersions of 20–100 m/s for a 10 GPa shock wave in Ni/Al mixtures and 5–70 m/s for a 5 GPa shock wave in Ti/Teflon mixtures. Particle velocity dispersions of this magnitude are thought to be the driving mechanism for initiation of chemical reactions in reactive solid mixtures. © 1998 American Institute of Physics.
    Type of Medium: Electronic Resource
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  • 8
    Electronic Resource
    Electronic Resource
    Woodbury, NY : American Institute of Physics (AIP)
    Applied Physics Letters 70 (1997), S. 3365-3367 
    ISSN: 1077-3118
    Source: AIP Digital Archive
    Topics: Physics
    Notes: A new 50 mm powder gun was used to reproduce and to extend the real-time observations of ultra-fast exothermic reactions in a Ni/Al powder mixture at the shock front. Shock profiles measured by a manganin gauge show that (1) the threshold pressure for reaction is about 14 GPa; (2) the initiation criteria based either on shock energy or melting are in contradiction with experimental evidence. © 1997 American Institute of Physics.
    Type of Medium: Electronic Resource
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  • 9
    Electronic Resource
    Electronic Resource
    Woodbury, NY : American Institute of Physics (AIP)
    Applied Physics Letters 61 (1992), S. 520-521 
    ISSN: 1077-3118
    Source: AIP Digital Archive
    Topics: Physics
    Notes: A recent investigation of powdered Ni-Al systems subject to shock loading has yielded evidence that reactions occur during the shock front. Time-resolved measurements of normal shock pressure indicate that an "excess pressure'' is generated possibly due to an exothermic reaction in the Ni-Al system. These reactions appear to occur during the 100 ns that represent the shock front. A clear reaction threshold is observed and corroborated by micrographs of the recovered samples.
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  • 10
    Electronic Resource
    Electronic Resource
    Palo Alto, Calif. : Annual Reviews
    Annual Review of Entomology 25 (1980), S. 49-71 
    ISSN: 0066-4170
    Source: Annual Reviews Electronic Back Volume Collection 1932-2001ff
    Topics: Biology
    Type of Medium: Electronic Resource
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