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  • 1
    Electronic Resource
    Electronic Resource
    Chichester : Wiley-Blackwell
    Organic Magnetic Resonance 30 (1992), S. S3 
    ISSN: 0749-1581
    Keywords: Transient NOE experiments ; Synchronous nutation experiments ; NAD stack interactions ; Chemistry ; Analytical Chemistry and Spectroscopy
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Cross-relaxation interactions between the nicotinamide moiety and the adenine moiety of NAD in D2O solution were unambiguously revealed by steady-state NOE experiments, transient NOE experiments and synchronous nutation experiments. The experimental results, which allow a concise description in terms of auto-relaxation and cross-relaxation, are interpreted as the result of a stacking interaction. Studies of 13C relaxation and investigations on ternary mixtures with 6-methylpurine give evidence for an inter- rather than intra-molecular stack interaction, at least in the NMR concentration range.
    Additional Material: 5 Ill.
    Type of Medium: Electronic Resource
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