ISSN:
0887-6266
Schlagwort(e):
diffusion, non-Fickian, in polymer-penetrant systems
;
transport of penetrants in polymers, model involving flux and relaxation in
;
penetrant diffusion in polymers, evolution of steep fronts in
;
Chemistry
;
Polymer and Materials Science
Quelle:
Wiley InterScience Backfile Collection 1832-2000
Thema:
Chemie und Pharmazie
,
Physik
Notizen:
We adapt a recently proposed model for non-Fickian diffusion of penetrants into polymers and use it to study a drug-delivery problem. The model modified Fick's diffusion equation by the addition of stress-induced flux. A stress evolution equation incorporating aspects of the Maxwell and Kelvin-Voigt viscoelastic stress models completes the model. The relaxation time in the polymer is taken as a function of the penetrant concentration. The system is studied under the assumption that the diffusivity is large. Singular perturbation techniques are used to show that the concentration and stress evolve diffusively for small time, but exhibit steep fronts in a narrow region within the domain for larger time. These predictions are verified numerically for specified parameter values. Finally, the equations are studied in the steady state and are found to predict the evolution of shocks.
Zusätzliches Material:
13 Ill.
Materialart:
Digitale Medien
URL:
http://dx.doi.org/10.1002/polb.1992.090300204
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